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CdSe/ZnS量子点发光二极管的衬底依赖性:刚性玻璃与柔性塑料衬底的对比研究

Substrate Dependence of CdSe/ZnS Quantum-Dot Light-Emitting Diodes: A Comparative Study between Rigid Glass and Flexible Plastic Substrates.

作者信息

Lee Seyoung, Kim Jimyoung, Lee Honyeon

机构信息

Department of Electronic Materials, Devices and Equipment Engineering, Soonchunhyang University, Asan 31538, Republic of Korea.

出版信息

Nanomaterials (Basel). 2023 May 31;13(11):1780. doi: 10.3390/nano13111780.

DOI:10.3390/nano13111780
PMID:37299683
原文链接:https://pmc.ncbi.nlm.nih.gov/articles/PMC10254519/
Abstract

The purpose of this study was to investigate the effect of substrate characteristics on the performance of quantum-dot light-emitting diodes (QLEDs) with the aim of developing high-performance flexible QLEDs. Specifically, we compared QLEDs made with a flexible polyethylene naphthalate (PEN) substrate to those made with a rigid glass substrate, using the same materials and structure except for the substrates. Our findings indicate that the PEN QLED had a 3.3 nm wider full width at half maximum and a 6 nm redshifted spectrum in comparison to the glass QLED. Additionally, the PEN QLED exhibited a 6% higher current efficiency, a flatter current efficiency curve, and a 2.25-V lower turn-on voltage, indicating superior overall characteristics. We attribute the spectral difference to the optical properties of the PEN substrate, such as light transmittance and refractive index. Our study also revealed that the electro-optical properties of the QLEDs were consistent with the electron-only device and transient electroluminescence results, which suggests that the improved charge injection properties of the PEN QLED were responsible. Overall, our study provides valuable insights into the relationship between substrate characteristics and QLED performance, which can be used to develop high-performance QLEDs.

摘要

本研究的目的是研究衬底特性对量子点发光二极管(QLED)性能的影响,旨在开发高性能的柔性QLED。具体而言,我们将采用柔性聚萘二甲酸乙二醇酯(PEN)衬底制成的QLED与采用刚性玻璃衬底制成的QLED进行了比较,除衬底外,使用相同的材料和结构。我们的研究结果表明,与玻璃QLED相比,PEN QLED的半高宽宽3.3 nm,光谱红移6 nm。此外,PEN QLED的电流效率高6%,电流效率曲线更平坦,开启电压低2.25 V,表明其整体特性更优越。我们将光谱差异归因于PEN衬底的光学特性,如透光率和折射率。我们的研究还表明,QLED的电光特性与仅电子器件和瞬态电致发光结果一致,这表明PEN QLED电荷注入特性的改善是原因所在。总体而言,我们的研究为衬底特性与QLED性能之间的关系提供了有价值的见解,可用于开发高性能QLED。

https://cdn.ncbi.nlm.nih.gov/pmc/blobs/d1d4/10254519/12896061a28f/nanomaterials-13-01780-g006.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/d1d4/10254519/9427f2767b02/nanomaterials-13-01780-g001.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/d1d4/10254519/e3c91e9e7fba/nanomaterials-13-01780-g002.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/d1d4/10254519/cfe5568ec334/nanomaterials-13-01780-g003.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/d1d4/10254519/42cdc68855f6/nanomaterials-13-01780-g004.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/d1d4/10254519/0efc41f29075/nanomaterials-13-01780-g005.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/d1d4/10254519/12896061a28f/nanomaterials-13-01780-g006.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/d1d4/10254519/9427f2767b02/nanomaterials-13-01780-g001.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/d1d4/10254519/e3c91e9e7fba/nanomaterials-13-01780-g002.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/d1d4/10254519/cfe5568ec334/nanomaterials-13-01780-g003.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/d1d4/10254519/42cdc68855f6/nanomaterials-13-01780-g004.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/d1d4/10254519/0efc41f29075/nanomaterials-13-01780-g005.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/d1d4/10254519/12896061a28f/nanomaterials-13-01780-g006.jpg

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本文引用的文献

1
Quantum Mechanical Analysis Based on Perturbation Theory of CdSe/ZnS Quantum-Dot Light-Emission Properties.基于微扰理论的CdSe/ZnS量子点发光特性的量子力学分析
Nanomaterials (Basel). 2022 Oct 13;12(20):3590. doi: 10.3390/nano12203590.
2
Transient Dynamics of Charges and Excitons in Quantum Dot Light-Emitting Diodes.量子点发光二极管中电荷与激子的瞬态动力学
Small. 2022 Jul;18(29):e2202290. doi: 10.1002/smll.202202290. Epub 2022 Jun 26.
3
Flexible CdSe/ZnS Quantum-Dot Light-Emitting Diodes with Higher Efficiency than Rigid Devices.
具有比刚性器件更高效率的柔性CdSe/ZnS量子点发光二极管。
Micromachines (Basel). 2022 Feb 7;13(2):269. doi: 10.3390/mi13020269.
4
Emerging Self-Emissive Technologies for Flexible Displays.用于柔性显示器的新兴自发光技术。
Adv Mater. 2020 Apr;32(15):e1902391. doi: 10.1002/adma.201902391. Epub 2019 Oct 9.
5
High-performance NiO/Ag/NiO transparent electrodes for flexible organic photovoltaic cells.用于柔性有机光伏电池的高性能NiO/Ag/NiO透明电极。
ACS Appl Mater Interfaces. 2014 Sep 24;6(18):16403-8. doi: 10.1021/am504806k. Epub 2014 Aug 29.