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钨酸铋BiWO₄:关于其结构、光物理和光催化性质的综述

Bismuth tungstate BiWO: a review on structural, photophysical and photocatalytic properties.

作者信息

Elaouni Aicha, El Ouardi M, BaQais A, Arab M, Saadi M, Ait Ahsaine H

机构信息

Laboratoire de Chimie Appliquée des Matériaux, Centre des Sciences des Matériaux, Faculty of Sciences, Mohammed V University in Rabat Morocco

Université de Toulon, AMU, CNRS, IM2NP CS 60584 Toulon Cedex 9 F-83041 France.

出版信息

RSC Adv. 2023 Jun 9;13(26):17476-17494. doi: 10.1039/d3ra01987j.

Abstract

This review paper provides a comprehensive overview of the recent trends in bismuth tungstate (BiWO) research, covering its structural, electrical, photoluminescent, and photocatalytic properties. The structural characteristics of bismuth tungstate are explored in detail, including its different allotropic crystal structures with respect to its isotypic materials. The electrical properties of bismuth tungstate, such as its conductivity and electron mobility, are also discussed, along with its photoluminescent properties. The photocatalytic activity of bismuth tungstate is a particular focus, with recent advances in doping and co-doping strategies with metals, rare earth and other elements summarized. The limitations and challenges of using bismuth tungstate as a photocatalyst are also examined, such as its low quantum efficiency and susceptibility to photodegradation. Finally, recommendations for future research directions are provided, including the need for further studies on the underlying mechanisms of photocatalytic activity, the development of more efficient and stable bismuth tungstate-based photocatalysts, and the exploration of new applications in fields such as water treatment and energy conversion.

摘要

这篇综述文章全面概述了钨酸铋(BiWO)研究的最新趋势,涵盖了其结构、电学、光致发光和光催化性能。详细探讨了钨酸铋的结构特征,包括相对于其同型材料的不同同质异形晶体结构。还讨论了钨酸铋的电学性质,如其导电性和电子迁移率,以及其光致发光性质。钨酸铋的光催化活性是一个特别关注的焦点,总结了近期在金属、稀土和其他元素的掺杂及共掺杂策略方面的进展。还研究了使用钨酸铋作为光催化剂的局限性和挑战,例如其低量子效率和光降解敏感性。最后,提供了未来研究方向的建议,包括需要进一步研究光催化活性的潜在机制、开发更高效稳定的基于钨酸铋的光催化剂,以及探索在水处理和能量转换等领域的新应用。

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