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基于生物杂交 AgCrO/rGO 的纳米复合材料的开发,具有稳定的浮选性能,可用作增强型光催化剂用于污水处理,并作为抗生素结合物用于抗菌评估。

Development of biohybrid AgCrO/rGO based nanocomposites with stable flotation properties as enhanced Photocatalyst for sewage treatment and antibiotic-conjugated for antibacterial evaluation.

机构信息

Department of Chemistry, E.R.K Arts and Science College, Erumiyampatti, Dharmapuri, Tamilnadu 636 905, India.

Department of Food Science and Technology, Seoul Women's University, 621 Hwarangno, Nowon-gu, Seoul, South Korea.

出版信息

Int J Biol Macromol. 2023 Jul 31;244:125303. doi: 10.1016/j.ijbiomac.2023.125303. Epub 2023 Jun 11.

Abstract

The proposed research outlines a facile method to synthesize Silver Chromate/reduced graphene oxide nanocomposites (AgCrO/rGO NCs) with a narrow dissemination size for the ecological treatment of hazardous organic dyes. The photodegradation performance toward the decontamination of model artificial methylene blue dye was assessed under solar light irradiation. The crystallinity, particle size, recombination of photogenerated charge carriers, energy gap and surface morphologies of synthesized nanocomposites were determined. The experiment objective is to use rGO nanocomposites to increase AgCrO photocatalytic efficiency in the solar spectrum. Tauc plots of ultraviolet-visible (UV-vis) spectrum were used to calculate the optical bandgap energy of the produced nanocomposites ∼1.52 eV, which resulted in a good photodegradation percentage of ∼92 % after 60 min irradiation of Solar light. At the same time, pure AgCrO and rGO nanomaterials showed ∼46 % and ∼ 30 %, respectively. The ideal circumstances were discovered by investigating the effects of several parameters, including catalyst loading and different pH levels, on the degradation of dyes. However, the final composites maintain their ability to degrade for up to five cycles. According to the investigations, AgCrO/rGO NCs are an effective photocatalyst and can be used as the ideal material to prevent water pollution. Furthermore, antibacterial efficacy for the hydrothermally synthesized nanocomposite was tested against gram-positive (+ve) bacteria viz. Staphylococcus aureus and gram-negative (-ve) bacteria viz. Escherichia coli. The maximum zone of inhibition for S. aureus and E. coli were 18.5 and 17 mm, respectively.

摘要

本研究提出了一种简便的方法,用于合成具有窄分散尺寸的银铬酸盐/还原氧化石墨烯纳米复合材料(AgCrO/rGO NCs),以用于生态处理危险有机染料。在太阳光照下,评估了其对模型人工亚甲基蓝染料的光降解性能。确定了合成纳米复合材料的结晶度、粒径、光生载流子复合、能隙和表面形态。实验目的是利用 rGO 纳米复合材料来提高 AgCrO 在太阳光谱中的光催化效率。使用紫外-可见(UV-vis)光谱的 Tauc 图来计算所制备纳米复合材料的光学带隙能约为 1.52 eV,这导致在太阳光照 60 分钟后光降解率约为 92%。同时,纯 AgCrO 和 rGO 纳米材料的光降解率分别约为 46%和 30%。通过研究催化剂负载量和不同 pH 值等几个参数对染料降解的影响,发现了理想的条件。然而,最终的复合材料仍保持其在五个循环内降解的能力。根据研究,AgCrO/rGO NCs 是一种有效的光催化剂,可以用作防止水污染的理想材料。此外,还测试了水热合成的纳米复合材料对革兰氏阳性(+ve)细菌金黄色葡萄球菌和革兰氏阴性(-ve)细菌大肠杆菌的抗菌效果。金黄色葡萄球菌和大肠杆菌的最大抑菌圈直径分别为 18.5 和 17 毫米。

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