Design of Intelligent Protective Composite Material with Stress Rate Sensitivity, Strong Interface Adhesion, and Recyclability.

Poly(dimethyl siloxane) (PDMS) elastomers play a significant role in smart materials, actuators, and flexible electronics. However, current PDMS lacks adhesion abilities and intelligent responsive properties, which limit its further application. In this study, the polydimethylsiloxane-ureidopyrimidinone impact hardening polymer (PDMS-UI) composites are manufactured by a dual cross-linking compositing tactic. PDMS, a chemically stable cross-linked network, acts as a framework owing to its excellent mechanical strength, whereas UI, a reversible dynamic physically cross-linked network with quadruple hydrogen bonding, endows the PDMS-UI with excellent self-healing ability (efficiency > 90%) and energy absorption (75.23%). Impressively, owing to multivalent hydrogen bonds, the PDMS-UI exhibits superior adhesion performance: the adhesion strength on various substrates exceed 150 kPa and that on the Ferrum substrate reaches 570 kPa. These outstanding properties make the PDMS-UI a potential candidate for application in both well-developed fields, such as, wearable protective materials, artificial skin and soft robotics.