Saura-Sanmartin Adrian
Departamento de Química Orgánica, Facultad de Química, Universidad de Murcia, 30100 Murcia, Spain.
Beilstein J Org Chem. 2023 Jun 14;19:873-880. doi: 10.3762/bjoc.19.64. eCollection 2023.
Light-responsive rotaxane-based solid-state materials are ideal scaffolds in order to develop smart materials due to the properties provided by the mechanical bond, such as control over the dynamics of the components upon application of external stimuli. This perspective aims to highlight the relevance of these materials, by pointing out recent examples of photoresponsive materials prepared from a rotaxanated architecture in which motion of the counterparts and/or macroscopic motion of the interlocked materials are achieved. Although further development is needed, these materials are envisioned as privileged scaffolds which will be used for different advanced applications in the area of molecular machinery.
基于光响应轮烷的固态材料由于机械键所赋予的特性，如在施加外部刺激时能够控制组件的动力学，是开发智能材料的理想支架。这篇综述旨在通过指出近期由轮烷结构制备的光响应材料的实例，突出这些材料的重要性，在这些实例中实现了对应物的运动和/或互锁材料的宏观运动。尽管还需要进一步发展，但这些材料被视为具有优势的支架，将用于分子机器领域的不同先进应用。
