Nonthermal plasma coupled with liquid-phase UV/Fe-C for chlorobenzene removal.

Catalyst poisoning problems limit the application of gas-solid non-thermal plasma (NTP) catalyzed decomposition of chlorinated volatile organic compounds (Cl-VOCs). To mitigate the catalyst deactivation, catalyst iron-loaded activated carbon (Fe-C) was added to the UV-activated liquid phase downstream of the NTP reactor (NTP + UV/Fe-C(L)) for the degradation of chlorobenzene (CB) in this study. The CB removal efficiency and mineralization efficiency (MR) of NTP + UV/Fe-C(L) were up to 94% and 68%, respectively, which were increased by 39% and 30% compared with the single NTP system. Compared with the conventional gas-solid NTP + UV/Fe-C(S) system, the stability of the NTP + UV/Fe-C(L) system was significantly improved due to the dissolved organic intermediates and low residuals on the catalyst surface. Reactive oxygen species ·OH and ·O dominated the decomposition of CB in the liquid phase, and with the help of UV, much more ·OH and ·O were produced by Fe-C catalytic O. In addition, Fe-C improved the removal of CB by increasing its absorption mass transfer coefficient from 0.0016 to 0.0157 s. The degradation pathway of CB in the NTP + UV/Fe-C(L) system was proposed based on the detected organic intermediates. Overall, this study provides a new tactic to solve the catalyst poisoning problem in the NTP catalytic oxidation of Cl-VOCs.