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经典力学中的能量均分定理与其量子力学相空间表述之间的对应关系。

Correspondence between the Energy Equipartition Theorem in Classical Mechanics and Its Phase-Space Formulation in Quantum Mechanics.

作者信息

Marulanda Esteban, Restrepo Alejandro, Restrepo Johans

机构信息

Instituto de Física, Universidad de Antioquia, Calle 70 No. 52-21, Medellín 050010, Colombia.

Group of Magnetism and Simulation, Instituto de Física, Universidad de Antioquia, A.A. 1226, Medellín 050010, Colombia.

出版信息

Entropy (Basel). 2023 Jun 15;25(6):939. doi: 10.3390/e25060939.

DOI:10.3390/e25060939
PMID:37372283
原文链接:https://pmc.ncbi.nlm.nih.gov/articles/PMC10297705/
Abstract

In classical physics, there is a well-known theorem in which it is established that the energy per degree of freedom is the same. However, in quantum mechanics, due to the non-commutativity of some pairs of observables and the possibility of having non-Markovian dynamics, the energy is not equally distributed. We propose a correspondence between what is known as the classical energy equipartition theorem and its counterpart in the phase-space formulation in quantum mechanics based on the Wigner representation. Further, we show that in the high-temperature regime, the classical result is recovered.

摘要

在经典物理学中,有一个著名的定理,该定理表明每个自由度的能量是相同的。然而,在量子力学中,由于某些可观测量对的不可对易性以及存在非马尔可夫动力学的可能性,能量并非均匀分布。我们基于维格纳表象提出了经典能量均分定理与其在量子力学相空间表述中的对应定理之间的一种对应关系。此外,我们表明在高温 regime 下,可以恢复经典结果。

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本文引用的文献

1
Quantum counterpart of energy equipartition theorem for a dissipative charged magneto-oscillator: Effect of dissipation, memory, and magnetic field.耗散带电磁振子能量均分定理的量子对应:耗散、记忆和磁场的影响
Phys Rev E. 2021 Dec;104(6-1):064112. doi: 10.1103/PhysRevE.104.064112.
2
Influence of non-Markovian dynamics in equilibrium uncertainty-relations.平衡不确定性关系中非马尔可夫动力学的影响。
J Chem Phys. 2019 Jan 21;150(3):034105. doi: 10.1063/1.5055061.
3
A semiclassical initial-value representation for quantum propagator and boltzmann operator.量子传播子和玻尔兹曼算符的半经典初值表示。
J Comput Chem. 2019 Apr 15;40(10):1161-1171. doi: 10.1002/jcc.25751. Epub 2018 Dec 27.
4
Partition of energy for a dissipative quantum oscillator.耗散量子振子的能量分配
Sci Rep. 2018 Oct 31;8(1):16080. doi: 10.1038/s41598-018-34385-9.