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基于激光诱导石墨烯的电化学传感器用于水中多菌灵的检测

Electrochemical Sensor Based on Laser-Induced Graphene for Carbendazim Detection in Water.

作者信息

Wang Li, Li Mengyue, Li Bo, Wang Min, Zhao Hua, Zhao Fengnian

机构信息

College of Chemistry and Materials Engineering, Beijing Technology and Business University, Beijing 100048, China.

出版信息

Foods. 2023 Jun 6;12(12):2277. doi: 10.3390/foods12122277.

DOI:10.3390/foods12122277
PMID:37372489
原文链接:https://pmc.ncbi.nlm.nih.gov/articles/PMC10297698/
Abstract

Carbendazim (CBZ) abuse can lead to pesticide residues, which may threaten the environment and human health. In this paper, a portable three-electrode sensor based on laser-induced graphene (LIG) was proposed for the electrochemical detection of CBZ. Compared with the traditional preparation method of graphene, LIG is prepared by exposing the polyimide film to a laser, which is easily produced and patterned. To enhance the sensitivity, platinum nanoparticles (PtNPs) were electrodeposited on the surface of LIG. Under optimal conditions, our prepared sensor (LIG/Pt) has a good linear relationship with CBZ concentration in the range of 1-40 μM, with a low detection limit of 0.67 μM. Further, the sensor shows good recovery rates for the detection of CBZ in wastewater, which provides a fast and reliable method for real-time analysis of CBZ residues in water samples.

摘要

多菌灵(CBZ)滥用会导致农药残留,这可能威胁环境和人类健康。本文提出了一种基于激光诱导石墨烯(LIG)的便携式三电极传感器,用于多菌灵的电化学检测。与传统的石墨烯制备方法相比,LIG是通过将聚酰亚胺薄膜暴露于激光下制备的,易于制备且可图案化。为了提高灵敏度,在LIG表面电沉积了铂纳米颗粒(PtNPs)。在最佳条件下,我们制备的传感器(LIG/Pt)与1-40μM范围内的多菌灵浓度具有良好的线性关系,检测限低至0.67μM。此外,该传感器对废水中多菌灵的检测具有良好的回收率,为水样中多菌灵残留的实时分析提供了一种快速可靠的方法。

https://cdn.ncbi.nlm.nih.gov/pmc/blobs/84b9/10297698/9f63b692c7f8/foods-12-02277-g005.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/84b9/10297698/f1c8c6338245/foods-12-02277-g001.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/84b9/10297698/407642fc15c3/foods-12-02277-g002.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/84b9/10297698/7bfaca394455/foods-12-02277-g003.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/84b9/10297698/bdbd1f212cb8/foods-12-02277-g004.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/84b9/10297698/9f63b692c7f8/foods-12-02277-g005.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/84b9/10297698/f1c8c6338245/foods-12-02277-g001.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/84b9/10297698/407642fc15c3/foods-12-02277-g002.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/84b9/10297698/7bfaca394455/foods-12-02277-g003.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/84b9/10297698/bdbd1f212cb8/foods-12-02277-g004.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/84b9/10297698/9f63b692c7f8/foods-12-02277-g005.jpg

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