Zhou Yingwu, Guo Wenhui, Zheng Shuyue, Xing Feng, Guo Menghuan, Zhu Zhongfeng
Guangdong Provincial Key Laboratory of Durability for Marine Civil Engineering, Shenzhen University, Shenzhen 518060, China.
Beijing Urban Construction Design and Development Group Co., Ltd., Beijing 100037, China.
Polymers (Basel). 2023 Jun 16;15(12):2701. doi: 10.3390/polym15122701.
In this study, sustainable engineered cementitious composites (ECC) exhibiting high tensile strength as well as high tensile strain capacity were successfully developed by incorporating polyethylene (PE) fiber, local recycled fine aggregate (RFA), and limestone calcined clay cement (LC). The improvement in tensile strength and tensile ductility was attributed to the self-cementing properties of RFA as well as the pozzolanic reaction between calcined clay and cement. Carbonate aluminates were also generated owing to the reaction between calcium carbonate in limestone and the aluminates in both calcined clay and cement. The bond strength between fiber and matrix was also enhanced. At the age of 150 days, the tensile stress-strain curves of ECC containing LC and RFA shifted from a bilinear model to a trilinear model, and the hydrophobic PE fiber exhibited hydrophilic bonding performance when embedded in RFA-LC-ECC matrix, which could be explained by the densified cementitious matrix as well as the refined pore structure of ECC. Moreover, the substitution of ordinary Portland cement (OPC) by LC resulted in energy consumption and equivalent CO emission reduction ratios of 13.61% and 30.34%, respectively, when the replacement ratio of LC is 35%. Therefore, PE fiber-reinforced RFA-LC-ECC demonstrates excellent mechanical performance as well as considerable environmental benefits.
在本研究中,通过掺入聚乙烯(PE)纤维、当地再生细集料(RFA)和石灰石煅烧粘土水泥(LC),成功开发出了具有高抗拉强度和高拉伸应变能力的可持续工程水泥基复合材料(ECC)。抗拉强度和拉伸延性的提高归因于RFA的自胶凝性能以及煅烧粘土与水泥之间的火山灰反应。由于石灰石中的碳酸钙与煅烧粘土和水泥中的铝酸盐之间的反应,还生成了碳酸盐铝酸盐。纤维与基体之间的粘结强度也得到了提高。在150天时,含LC和RFA的ECC的拉伸应力-应变曲线从双线性模型转变为三线性模型,疏水性PE纤维在嵌入RFA-LC-ECC基体时表现出亲水性粘结性能,这可以用致密的水泥基体以及ECC细化的孔隙结构来解释。此外,当LC的替代率为35%时,用LC替代普通硅酸盐水泥(OPC)可使能耗和等效CO排放量分别降低13.61%和30.34%。因此,PE纤维增强的RFA-LC-ECC具有优异的力学性能以及可观的环境效益。