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荷兰多环芳烃的湿沉降

Wet deposition of polycyclic aromatic hydrocarbons in The Netherlands.

作者信息

den Hollander H, van de Meent D, van Noort P, Wondergem E

出版信息

Sci Total Environ. 1986 Jul;52(3):211-9. doi: 10.1016/0048-9697(86)90121-x.

DOI:10.1016/0048-9697(86)90121-x
PMID:3738501
Abstract

The concentrations of 11 polycyclic aromatic hydrocarbons (PAH) in rainwater at four locations in the Netherlands in 1983 are reported. From literature data for these PAH in air, scavenging ratios were calculated. For PAH predominantly adsorbed on aerosols these scavenging ratios are in the range 3-13 X 10(4). For phenanthrene the scavenging ratios are in the range 0.35-2.5 X 10(4). The data for the aerosol-associated PAH at the various locations are discussed in terms of aerosol in-cloud scavenging, and are compared with reported data from Belgium and Germany. The scavenging ratios for phenanthrene are compared with those predicted on the basis of Henry's law constant and were found to be less than one order of magnitude higher than expected, possibly because of enhanced aqueous solubility.

摘要

报告了1983年荷兰四个地点雨水中11种多环芳烃(PAH)的浓度。根据空气中这些PAH的文献数据,计算了清除率。对于主要吸附在气溶胶上的PAH,这些清除率在3 - 13×10⁴范围内。对于菲,清除率在0.35 - 2.5×10⁴范围内。从气溶胶云内清除的角度讨论了不同地点与气溶胶相关的PAH数据,并与比利时和德国报告的数据进行了比较。将菲的清除率与根据亨利定律常数预测的清除率进行了比较,发现比预期高不到一个数量级,可能是由于水溶性增强。

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