Hubei Key Laboratory of Coal Conversion and New Carbon Material, School of Chemistry and Chemical Engineering, Wuhan University of Science and Technology, Wuhan 430081, China.
Jingzhou Conservation Center, Jingzhou 434020, China.
Langmuir. 2023 Jul 18;39(28):9912-9923. doi: 10.1021/acs.langmuir.3c01144. Epub 2023 Jun 30.
Superhydrophobic cotton fabrics have a lot of potential for use in practical settings. The majority of superhydrophobic cotton fabrics, however, only serve one purpose and are made from fluoride or silane chemicals. Therefore, it remains a challenge to develop multifunctional superhydrophobic cotton fabrics using environmentally friendly raw materials. In this study, chitosan (CS), amino carbon nanotubes (ACNTs), and octadecylamine (ODA) were used as raw materials to create CS-ACNTs-ODA photothermal superhydrophobic cotton fabrics. The cotton fabric that was created showed a remarkable superhydrophobic property with a water contact angle of 160.3°. The surface temperature of CS-ACNTs-ODA cotton fabric can rise by up to 70 °C when exposed to simulated sunlight, demonstrating the fabric's remarkable photothermal capabilities. Additionally, the coated cotton fabric is capable of quick deicing. Ice particles (10 μL) melted and began to roll down in 180 s under the light of "1 sun". The cotton fabric exhibits good durability and adaptability in terms of mechanical qualities and washing tests. Moreover, the CS-ACNTs-ODA cotton fabric displays a separation efficacy of more than 91% when used to treat various oil and water mixtures. We also impregnate the coating on polyurethane sponges, which can quickly absorb and separate oil and water mixtures.
超疏水棉织物在实际应用中有很大的潜力。然而,大多数超疏水棉织物只有一种用途,并且是由氟化物或硅烷化学物质制成的。因此,用环保原料开发多功能超疏水棉织物仍然是一个挑战。在这项研究中,壳聚糖(CS)、氨基碳纳米管(ACNTs)和十八胺(ODA)被用作原料来制备 CS-ACNTs-ODA 光热超疏水棉织物。所制备的棉织物表现出显著的超疏水性,水接触角为 160.3°。当暴露于模拟阳光下时,CS-ACNTs-ODA 棉织物的表面温度可升高 70°C,显示出其出色的光热性能。此外,涂覆的棉织物能够快速除冰。在“1 个太阳”的光线下,10 μL 的冰粒在 180 s 内融化并开始滚落。棉织物在机械性能和洗涤测试方面具有良好的耐久性和适应性。此外,CS-ACNTs-ODA 棉织物在处理各种油和水混合物时的分离效率超过 91%。我们还将涂层浸渍到聚氨酯海绵上,它可以快速吸收和分离油和水混合物。