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一种用于快速准确检测银离子的胞苷修饰的表面活性剂锚定液晶微滴传感器。

A Cytidine-Modified surfactant anchored liquid crystal Droplet-Based sensor for rapid and accurate detection of silver ions.

作者信息

Zhang Guannan, Zhao Wenting, Liu Wenzhao, Zhou Jun, Wu Zhaoyang

机构信息

State Key Laboratory of Chemo/Bio-sensing and Chemo-metrics, College of Chemistry and Chemical Engineering, Hunan University, Changsha 410082, People's Republic of China.

State Key Laboratory of Chemo/Bio-sensing and Chemo-metrics, College of Chemistry and Chemical Engineering, Hunan University, Changsha 410082, People's Republic of China.

出版信息

J Colloid Interface Sci. 2023 Nov 15;650(Pt A):58-66. doi: 10.1016/j.jcis.2023.06.111. Epub 2023 Jun 19.

Abstract

Liquid crystal (LC) droplets exhibit unique and sensitive response behaviors to surface absorptions, making them promising candidates for sensing aplications. Here, we have developed a label-free, portable, and cost-effective sensor for the specific and rapid detection of silver ions (Ag) in drinking-water samples. To achieve this, we have modified cytidine into a surfactant (denoted as C10-M-C) and anchored it onto the surface of LC droplets. The specific binding ability between cytidine and Ag enables LC droplets anchored with C10-M-C to respond rapidly and specifically to Ag ions. Furthermore, the sensitivity of the response meets requirements for the harmless concentration of Ag in drinking-water. The sensor we developed is label-free, portable, and cost-effectively. We believe that the sensor reported here can be applied to the detection of Ag in drinking-water and environmental samples.

摘要

液晶(LC)液滴对表面吸附表现出独特而灵敏的响应行为,使其成为传感应用的有前途的候选者。在此,我们开发了一种用于饮用水样品中银离子(Ag)特异性快速检测的无标记、便携式且经济高效的传感器。为此,我们将胞苷修饰成一种表面活性剂(记为C10-M-C)并将其锚定在LC液滴表面。胞苷与银之间的特异性结合能力使锚定有C10-M-C的LC液滴能够对银离子快速且特异性地做出响应。此外,响应的灵敏度满足饮用水中银无害浓度的要求。我们开发的传感器是无标记、便携式且经济高效的。我们相信这里报道的传感器可应用于饮用水和环境样品中银的检测。

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