-具有可脱保护取代基的氟苯磺酰亚胺（NFSI）类似物：β-氟胺的合成 苯乙烯的催化氨基氟化反应
-Fluorobenzenesulfonimide (NFSI) analogs with deprotectable substituents: synthesis of β-fluoroamines catalytic aminofluorination of styrenes.
作者信息
Ito Yuki, Adachi Akiya, Aikawa Kohsuke, Nozaki Kyoko, Okazoe Takashi
机构信息
Department of Chemistry and Biotechnology, Graduate School of Engineering, The University of Tokyo, 2-11-16 Yayoi, Bunkyo-ku, Tokyo 113-8656, Japan.
Department of Chemistry and Biotechnology, Graduate School of Engineering, The University of Tokyo, 7-3-1 Hongo, Bunkyo-ku, Tokyo 113-8656, Japan.
出版信息
Chem Commun (Camb). 2023 Jul 25;59(60):9195-9198. doi: 10.1039/d3cc02292g.
The palladium-catalyzed aminofluorination of styrenes using novel -fluorobenzenesulfonimide (NFSI) derivatives with deprotectable substituents, and the selective deprotection and transformation of the resulting products into amines under mild reaction conditions are herein disclosed.
本文公开了使用具有可脱保护取代基的新型氟苯磺酰亚胺（NFSI）衍生物对苯乙烯进行钯催化的氨基氟化反应，以及在温和反应条件下将所得产物选择性脱保护并转化为胺的方法。
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