Carroll Robert C, Harrowven David C, Pearce James E, Coles Simon J
School of Chemistry, University of Southampton, University Road, Southampton, Hampshire SO17 1BJ, United Kingdom.
IUCrJ. 2023 Jul 1;10(Pt 4):497-508. doi: 10.1107/S2052252523005146.
Utilization of the crystalline sponge {[(ZnI)(tpt)·x(solvent)]} method has enabled characterization of a novel family of synthetic organic oils. The systematic structural differences and diversity of functional groups offered by 13 related molecular adsorbates provide a detailed quantitative understanding of the relationship between the guest structure, its conformation, and the type of intermolecular interactions adopted with neighbouring guests and the host framework. This analysis is extended to assess the connection of these factors to the resulting quality indicators for a particular molecular structure elucidation.
利用结晶海绵{[(ZnI)(tpt)·x(溶剂)]}方法能够对一类新型合成有机油进行表征。13种相关分子吸附物所呈现的系统结构差异和官能团多样性，为深入定量理解客体结构、其构象以及与相邻客体和主体骨架所采用的分子间相互作用类型之间的关系提供了依据。该分析进一步扩展，以评估这些因素与特定分子结构解析所得质量指标之间的联系。
