Hollow mesoporous cubic silica self-assembling into photonic crystals with rhombohedral lattices and vivid structural colors for anti-counterfeiting.

Colloidal photonic crystals (PCs) feature face-centered cubic (FCC) lattices since spherical particles are usually used as building blocks; however, constructing structural colors originating from PCs with non-FCC lattices is still a big challenge due to the difficulty in preparing non-spherical particles with tunable morphologies, sizes, uniformity, and surface properties and assembling them into ordered structures. Here, uniform, positively charged, and hollow mesoporous cubic silica particles (hmc-SiO) with tunable sizes and shell thicknesses prepared by a template approach are used to self-assemble into PCs with rhombohedral lattice. The reflection wavelengths and structural colors of the PCs can be controlled by altering the sizes or the shell thicknesses of the hmc-SiO. Additionally, photoluminescent PCs have been fabricated by taking the advantage of the click chemistry between amino silane and isothiocyanate of a commercial dye. The PC pattern achieved by a hand-writing way with the solution of the photoluminescent hmc-SiO instantly and reversibly shows the structural color under visible light but a different photoluminescent color under UV illumination, which is useful for anticounterfeiting and information encryption. The non-FCC structured and photoluminescent PCs will upgrade the basic understanding of the structural colors and facilitate their applications in optical devices, anti-counterfeiting, and so forth.