Sánchez Juárez A, Carrión Fabián, Carrión Javier, Castillo Darwin, Padilla-Martínez J P, Cruz-Félix Ángel
Departamento de Química, Universidad Técnica Particular de Loja, Loja 1101608, Ecuador.
Instituto de Ciencias, Benemérita Universidad Autónoma de Puebla, Puebla 72960, Mexico.
Sensors (Basel). 2023 Jun 15;23(12):5602. doi: 10.3390/s23125602.
In this research, we present a prototype optical system that offers significant advances in detecting hydrochloric acid (HCl) and ammonia (NH3) vapors. The system utilizes a natural pigment sensor based on that is securely attached to a glass surface support. Through extensive development and testing with HCl (37% aqueous solution) and NH (29% aqueous solution) solutions, we have successfully demonstrated the effectiveness of our sensor. To facilitate the detection process, we have developed an injection system that exposes pigment films to the targeted vapors. The interaction between the vapors and the pigment films triggers a distinct color change, which is then analyzed by the detection system. By capturing the transmission spectra of the pigment film, our system allows a precise comparison of these spectra at different concentrations of the vapors. Our proposed sensor exhibits remarkable sensitivity, allowing the detection of HCl at a concentration of 0.009 ppm using only 100 µL (2.3 mg) of pigment film. In addition, it can detect NH at a concentration of 0.03 ppm with a 400 µL (9.2 mg) pigment film. Integrating as a natural pigment sensor in an optical system opens up new possibilities for detecting hazardous gases. The simplicity and efficiency of our system, combined with its sensitivity, make it an attractive tool in environmental monitoring and industrial safety applications.
在本研究中,我们展示了一种原型光学系统,该系统在检测盐酸(HCl)和氨气(NH₃)蒸汽方面取得了重大进展。该系统采用了一种基于天然色素的传感器,该传感器牢固地附着在玻璃表面支撑物上。通过对HCl(37%水溶液)和NH₃(29%水溶液)溶液进行广泛的开发和测试,我们成功证明了传感器的有效性。为了便于检测过程,我们开发了一种注射系统,使色素膜暴露于目标蒸汽中。蒸汽与色素膜之间的相互作用引发明显的颜色变化,然后由检测系统进行分析。通过捕获色素膜的透射光谱,我们的系统能够精确比较不同浓度蒸汽下的这些光谱。我们提出的传感器具有显著的灵敏度,仅使用100微升(2.3毫克)色素膜就能检测到浓度为0.009 ppm的HCl。此外,使用400微升(9.2毫克)色素膜时,它能够检测到浓度为0.03 ppm的NH₃。将天然色素传感器集成到光学系统中为检测有害气体开辟了新的可能性。我们系统的简单性、效率及其灵敏度使其成为环境监测和工业安全应用中有吸引力的工具。