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用于气体捕获与分离的具有零连接体配体的超微孔稳定金属有机框架材料

Ultra-Microporous and Stable MOFs with Zero-Linker Ligands for Gas Capture and Separation.

作者信息

Chan Shook Pui, Zhang Yugen

机构信息

Institute of Sustainability for Chemicals, Energy and Environment (ISCE2), Agency for Science, Technology and Research (A*STAR), 1 Pesek Road Jurong Island, Singapore, 627833, Republic of Singapore.

出版信息

Chemistry. 2023 Sep 26;29(54):e202301279. doi: 10.1002/chem.202301279. Epub 2023 Aug 21.

Abstract

Zero-linker ligands have maximized the size coordination efficiency of the metal ions in MOF framework which is important in constructing ultra-microporous MOFs with high stability and density, a bridge between zeolites and traditional MOFs. This article highlighted several recently developed ultra-microporous MOFs with zero-linker ligands for gas capture and separation.

摘要

零连接体配体使金属离子在金属有机框架(MOF)中的尺寸配位效率最大化,这对于构建具有高稳定性和密度的超微孔MOF至关重要,超微孔MOF是沸石与传统MOF之间的桥梁。本文重点介绍了几种最近开发的带有零连接体配体的超微孔MOF,用于气体捕获和分离。

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