Mitigation of Cd(II) contamination in aqueous solution and soil by multifunctional hydroxyapatite/sludge biochar composite.

Biochar with well-developed pore structure is an ideal carrier for easily agglomerated hydroxyapatite (HAP). Hence, a novel multifunctional hydroxyapatite/sludge biochar composite (HAP@BC) was synthesized by chemical precipitation method and used for mitigating Cd(II) contamination form aqueous solution/soil. Compared to sludge biochar (BC), HAP@BC exhibited rougher and more porous surface. Meanwhile, the HAP was dispersed on the sludge biochar surface, which reduced the agglomeration of HAP. The adsorption performance of HAP@BC on Cd(II) was better than that of BC under the influence of different single-factor batch adsorption experiments. Moreover, the Cd(II) adsorption behavior by BC and HAP@BC was uniform monolayer adsorption, and this reaction process was endothermic and spontaneous. The Cd(II) maximum adsorption capacities of BC and HAP@BC were 79.96 and 190.72 mg/g at 298 K, respectively. Moreover, the Cd(II) adsorption mechanism on BC and HAP@BC included complexation, ion exchange, dissolution-precipitation and Cd(II)-π interaction. According to the semi-quantitative analysis, ion exchange was the main mechanism for Cd(II) removal by HAP@BC. Notably, HAP played a role in the Cd(II) removal by dissolution-precipitation and ion exchange. This result suggested that there was a synergistic effect between HAP and sludge biochar for the Cd(II) removal. HAP@BC reduced the leaching toxicity of Cd(II) in soil better than BC, indicating that the HAP@BC was able to mitigate Cd(II) contamination in soil more effectively. This work demonstrated that sludge biochar was an ideal carrier for dispersed HAP and provided an effective HAP/biochar composite for the mitigation of Cd(II) contamination in aqueous solution/soil.