Yin Shiwen, Ge Shimeng, Li Xiaoshuai, Zhao Yunlu, Ma Hongmei, Sun Yubao
Department of Applied Physics, Hebei University of Technology, Tianjin 300401, P. R. China.
School of Electronic and Information Engineering, Hebei University of Technology, Tianjin 300401, P. R. China.
ACS Appl Mater Interfaces. 2023 Jul 26;15(29):35302-35310. doi: 10.1021/acsami.3c07287. Epub 2023 Jul 12.
The planar state of a cholesteric liquid crystal (CLC) often exhibits oily streak defects, which negatively impact the characteristics of precision optics, including transmission and selective reflection. In this paper, we introduced polymerizable monomers into liquid crystals and examined the effects of monomer concentration, polymerization light intensity, and chiral dopant concentration on oily streak defects in CLC. With the proposed method of heating cholesteric liquid crystals to the isotropic phase followed by rapid cooling, the oil streak defects presented in the liquid crystal can be successfully eliminated. Furthermore, a stable focal conic state can be obtained by a slow cooling process. Two stable states with different optical properties can be obtained based on the cholesteric liquid crystal at different cooling rates, which makes it possible to detect whether the stored procedure of temperature-sensitive material is qualified. These findings have widespread applications in devices that require a planar state without oily streak defects and temperature-sensitive detection devices.
胆甾相液晶(CLC)的平面态常出现油纹缺陷,这对精密光学器件的特性产生负面影响,包括透射和选择性反射。在本文中,我们将可聚合单体引入液晶中,并研究了单体浓度、聚合光强度和手性掺杂剂浓度对CLC中油纹缺陷的影响。通过将胆甾相液晶加热到各向同性相然后快速冷却的方法,液晶中出现的油纹缺陷能够被成功消除。此外,通过缓慢冷却过程可以获得稳定的焦锥态。基于胆甾相液晶在不同冷却速率下可获得两种具有不同光学性质的稳定状态,这使得检测温度敏感材料的存储过程是否合格成为可能。这些发现广泛应用于需要无油纹缺陷平面态的器件以及温度敏感检测器件。