Fakher Sherif, Khlaifat Abdelaziz Lafi
Petroleum and Energy Engineering Department, School of Sciences and Engineering, American University in Cairo, New Cairo 11835, Egypt.
Polymers (Basel). 2023 Jul 5;15(13):2950. doi: 10.3390/polym15132950.
Polymers are one of the most widely used chemicals in the oil and gas industry. They are used for mobility control in enhanced oil recovery, in conformance control as a cross-linked plugging agent, as a fracking fluid for fracture propagation and proppant transportation, and in drilling fluids as an additive for drilling mud enhancement. This research characterizes the polymer injectivity in different pore sizes under different conditions and evaluates the polymer conditions after injection. Based on this, the ability to reinject the polymer in the porous media is discussed. The factors studied include the pore size, the polymer concentration, the polymer injection flowrate, and polymer injectivity. When the porous media size was reduced to 1.59 mm (1/16th of an inch), the injectivity value reduced significantly, reaching less than 0.2 mL/min/psi and the polymer degradation increased primarily due to shearing. Results also showed that the polymers underwent four main degradations during injection including dehydration, syneresis, shearing, and excessive hydrolysis. In continuous fractures, the degradation is a strong function of the fracture size, length, and the polymer structure. The experimental results showed that one or more of the polymer degradations resulted in the inability to reinject the polymer in most cases.
聚合物是石油和天然气行业中使用最广泛的化学品之一。它们用于提高采收率中的流度控制、作为交联堵漏剂用于调剖、作为压裂液用于裂缝扩展和支撑剂输送,以及作为钻井液添加剂用于增强钻井泥浆性能。本研究表征了不同条件下聚合物在不同孔径中的注入能力,并评估了注入后聚合物的状态。基于此,讨论了在多孔介质中重新注入聚合物的能力。所研究的因素包括孔径、聚合物浓度、聚合物注入流速和聚合物注入能力。当多孔介质尺寸减小到1.59毫米(1/16英寸)时,注入能力值显著降低,降至小于0.2毫升/分钟/磅力,并且聚合物降解主要由于剪切作用而增加。结果还表明,聚合物在注入过程中经历了四种主要降解,包括脱水、离浆、剪切和过度水解。在连续裂缝中,降解强烈取决于裂缝尺寸、长度和聚合物结构。实验结果表明,在大多数情况下,一种或多种聚合物降解导致无法重新注入聚合物。