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壳聚糖改性技术对纺织品抗菌性能的影响研究。

Study on the Effect of Chitosan Modification Technology on Antibacterial Properties of Textiles.

机构信息

College of Textile and Clothing Engineering, Soochow University, Suzhou, 215123, China.

School of Pharmaceutical and Environmental Engineering, Nantong Vocational University, Nantong, 226007, China.

出版信息

Appl Biochem Biotechnol. 2024 Apr;196(4):1966-1976. doi: 10.1007/s12010-023-04621-8. Epub 2023 Jul 15.

Abstract

The chitosan is fixed in an amide group of activated carboxyl groups and biological primary amino groups of nonwoven PET for antibacterial properties. Uncoated materials have fewer wetting properties and are less biocompatible. The objectives of the study were to evaluate surface chemical compositions and biocompatibility, antibacterial, and hydrophilic properties of polyester fabrics grafted with chitosan oligomers and after being activated by atmospheric pressure plasmas. A 2% 14.8 mg/cm uncolored PET woven fabric was dissolved in chitosan solution. Atmospheric pressure plasmas were used to activate polyester fabrics grafted with chitosan oligomers on both sides. Cell proliferation assay was performed for the biocompatibility study. The American Association of Textile Chemists and Colorists method was used to measure the width of the antibacterial zone and the Japanese Industrial Standard was used to count the number of bacterial colonies. Chitosan-coated and -activated uncolored PET woven fabric showed fewer percentage free carbon (p < 0.0001), higher percentage free oxygen to free carbon ratio (p < 0.0001), higher percentage free nitrogen to free carbon ratio (p = 0.0453), and higher percentage free oxygen plus free nitrogen to free carbon ratio (p < 0.0001) than untreated PET woven fabric. The dynamic contact angle of a water droplet and the wicking time were shorter for chitosan-coated and -activated uncolored PET woven fabric than untreated PET weaved fabric (p < 0.0001 for all). Chitosan coating leads to PET woven fabric being higher biocompatible, wettable, and antibacterial than untreated PET woven fabric.

摘要

壳聚糖通过酰胺基团固定在非织造 PET 的活化羧基和生物伯氨基上,从而具有抗菌性能。未涂层的材料润湿性较差,生物相容性也较差。本研究的目的是评估聚酯纤维经壳寡糖接枝和常压等离子体活化后的表面化学成分、生物相容性、抗菌和亲水性能。将 2%、14.8mg/cm 的未染色 PET 机织布溶解在壳聚糖溶液中。使用常压等离子体对两侧接枝壳寡糖的聚酯纤维进行活化。采用细胞增殖试验进行生物相容性研究。采用美国纺织化学家和染色家协会方法测量抗菌带的宽度,采用日本工业标准计数细菌菌落数。与未经处理的 PET 机织布相比,壳聚糖涂层和活化的未染色 PET 机织布的游离碳百分比(p<0.0001)更低,游离氧与游离碳的比值(p<0.0001)更高,游离氮与游离碳的比值(p=0.0453)更高,游离氧加游离氮与游离碳的比值(p<0.0001)更高。与未经处理的 PET 机织布相比,壳聚糖涂层和活化的未染色 PET 机织布的水滴动态接触角和导湿时间更短(所有 p<0.0001)。壳聚糖涂层使 PET 机织布的生物相容性、润湿性和抗菌性均高于未经处理的 PET 机织布。

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