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计算研究沼气燃烧中的 NO 排放。

Computational investigation of NO emission in biogas combustion.

机构信息

Department of Chemical and Process Engineering, University of Moratuwa, Moratuwa, Sri Lanka.

Technische Hochschule Nürnberg, Georg Simon Ohm, Nürnberg, Germany.

出版信息

Environ Sci Pollut Res Int. 2023 Aug;30(38):89548-89558. doi: 10.1007/s11356-023-28607-5. Epub 2023 Jul 15.

Abstract

Landfills and anaerobic digesters in the waste treatment processes generate biogas. Biogas can be used as a fuel and excess biogas is typically burned in a flare to reduce the greenhouse effect. However, burning biogas produces several pollutants, including CO, NO, and SO. To minimize these emissions, the amount of excess air used in the combustion process needs to be considered, which has a significant impact on NO emissions. This study developed a Computational Fluid Dynamics (CFD) model to simulate a small-scale biogas combustion system and analyses the effect of excess air on heat output and NO emissions during biogas combustion. The GRI-Mech reaction mechanism was used to simulate reactions, and the model was validated by comparing it to experimental data from the DLR-Stuttgart CH/H/N Jet Flame. To reduce computational costs, a Tabulation of Dynamic Adaptive Chemistry (TDAC) algorithm was used to dynamically adapt the reaction mechanism in real time. Turbulence in the DLR flame was simulated using Reynolds-Averaged Navier-Stokes (RANS). The CFD model used a co-flow of a natural draft to provide additional air, while the air was premixed with fuel. The CFD model was used to simulate various premixed equivalent ratios, and the resulting emissions and heat outputs were compared. The study found that the optimal premixed equivalent ratio for the studied system was between 0.85 and 1.1, as this range produced the highest temperature and lowest NO emissions. This model facilitates emission analysis of gas-phase combustion systems.

摘要

垃圾填埋场和厌氧消化器在废物处理过程中会产生沼气。沼气可用作燃料,过量的沼气通常在火炬中燃烧以减少温室效应。然而,燃烧沼气会产生多种污染物,包括 CO、NO 和 SO。为了最大限度地减少这些排放,需要考虑燃烧过程中使用的过量空气量,这对 NO 排放有重大影响。本研究开发了计算流体动力学 (CFD) 模型来模拟小型沼气燃烧系统,并分析过量空气对沼气燃烧过程中热输出和 NO 排放的影响。使用 GRI-Mech 反应机制来模拟反应,并通过与 DLR-Stuttgart CH/H/N 射流的实验数据进行比较来验证模型。为了降低计算成本,使用了动态自适应化学制表 (TDAC) 算法来实时动态适应反应机制。使用雷诺平均纳维-斯托克斯 (RANS) 模拟 DLR 火焰中的湍流。CFD 模型使用自然通风的逆流来提供额外的空气,同时空气与燃料预混。CFD 模型用于模拟各种预混当量比,比较了由此产生的排放和热输出。研究发现,研究系统的最佳预混当量比在 0.85 到 1.1 之间,因为这个范围内产生的温度最高,NO 排放最低。该模型有助于对气相燃烧系统进行排放分析。

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