Szyling Jakub, Szymańska Aleksandra, Walkowiak Jędrzej
Centre for Advanced Technology, Adam Mickiewicz University, Uniwersytetu Poznańskiego 10, 61-614 Poznan, Poland.
Faculty of Chemistry, Adam Mickiewicz University, Uniwersytetu Poznańskiego 8, 61-614 Poznan, Poland.
Chem Commun (Camb). 2023 Aug 1;59(62):9541-9544. doi: 10.1039/d3cc02695g.
An efficient and facile one-pot protocol to access enynylboronates a Pt-catalyzed diboration/protodeboration strategy has been developed. The reaction is suitable for various silylsubstituted symmetrical and unsymmetrical 1,3-diynes, leading to π-conjugated organoboron compounds with excellent regio- and stereoselectivity.
