Parr Joseph M, White Andrew J P, Crimmin Mark R
Molecular Sciences Research Hub, Department of Chemistry, Imperial College London, 82 Wood Lane, White City, Shepherds Bush, London, W12 0BZ, UK.
Chem Commun (Camb). 2023 Aug 10;59(65):9840-9843. doi: 10.1039/d3cc03009a.
Reaction of a molecular calcium hydride with a series of group 9 dicarbonyl complexes [M(η-CMe)(CO)] (M = Co, Rh, Ir) led to the formation of both mono(formyl) and bis(formyl) complexes. The bis(formyl) complexes are unique. They have been characterised by multinuclear NMR spectroscopy and examples have been crystallographically characterised for the first time.
分子氢化钙与一系列第9族二羰基配合物[M(η-CMe)(CO)]（M = Co、Rh、Ir）反应生成了单（甲酰基）和双（甲酰基）配合物。双（甲酰基）配合物很独特。它们已通过多核核磁共振光谱进行了表征，并且首次对一些实例进行了晶体学表征。
