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采用生石灰调理油性冷轧轧机污泥以改善脱水性能:优化与机理研究。

Oily cold rolling mill sludge conditioned by quicklime to improve dewatering performance: optimization and mechanism study.

机构信息

School of Minerals Processing and Bioengineering, Central South University, Changsha, 410083, Hunan, China.

出版信息

Environ Sci Pollut Res Int. 2023 Aug;30(39):91125-91139. doi: 10.1007/s11356-023-28430-y. Epub 2023 Jul 20.

Abstract

Dewatering is critical to oily cold rolling mill (CRM) sludge treatment. Therefore, finding an efficient, energy-saving, and applicable dewatering technology for oily CRM sludge is still urgent. This study investigated the performance of quicklime as a conditioning agent for oily CRM sludge conditioning and dewatering. The interactive effects of quicklime dosage, temperature, and time on filter cake's specific resistance to filtration (SRF) and the dewatering rate of oily CRM sludge were studied by response surface methodology (RSM). The optimal parameters for conditioning oily CRM sludge were quicklime dosage of 18.7%, temperature of 54 °C, and time of 43.3 min, which resulted in filter cake SRF of 0.50 × 10 m/kg and dewatering rate of 61.2%. The viscosity of oily CRM sludge could be reduced by 90% after conditioned with quicklime, which caused by the neutralization or hydrolysis of high viscosity organic matter in the oil phase with quicklime to produce low viscosity organic matter. The study indicated the excellent performance of quicklime as a conditioning agent for oily CRM sludge treatment and provided an effective route for the recycling of the oily CRM sludge for steel production.

摘要

脱水对于含油冷轧轧机(CRM)污泥处理至关重要。因此,寻找一种高效、节能且适用的含油 CRM 污泥脱水技术仍然迫在眉睫。本研究探讨了生石灰作为含油 CRM 污泥调理和脱水的调理剂的性能。通过响应面法(RSM)研究了生石灰用量、温度和时间对滤饼比阻(SRF)和含油 CRM 污泥脱水率的交互影响。含油 CRM 污泥的最佳调理参数为生石灰用量 18.7%、温度 54°C 和时间 43.3 分钟,此时滤饼比阻为 0.50×10 m/kg,脱水率为 61.2%。生石灰调理后,含油 CRM 污泥的粘度可降低 90%,这是由于生石灰与油相中的高粘度有机物发生中和或水解反应,生成低粘度有机物所致。研究表明,生石灰作为含油 CRM 污泥处理的调理剂具有优异的性能,为钢铁生产中含油 CRM 污泥的回收提供了有效的途径。

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