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猪粪与木质纤维素废物共水热碳化:生物质废物整体增值的新策略。

Co-hydrothermal carbonization of swine manure and lignocellulosic waste: A new strategy for the integral valorization of biomass wastes.

机构信息

Chemical Engineering Department, Universidad Autónoma de Madrid, 28049 Madrid, Spain; Arquimea-Agrotech, 28400 Collado Villalba, Madrid, Spain.

Chemical Engineering Department, Universidad Autónoma de Madrid, 28049 Madrid, Spain.

出版信息

Waste Manag. 2023 Sep 1;169:267-275. doi: 10.1016/j.wasman.2023.07.018. Epub 2023 Jul 22.

Abstract

Co-hydrothermal carbonization (co-HTC) is a promising strategy to improve hydrothermal carbonization (HTC) of low-quality wastes. HTC of swine manure (SM), with high N (2.9 wt%), S (0.7 wt%) and ash (22.6 wt%) contents, as well as low C (35.6 wt%) and higher heating value (HHV; 14.3 MJ kg), resulted in a hydrochar with unsuitable characteristics as a solid fuel. Co-HTC of SM and garden and park waste (GPW) improved hydrochar properties (C content (43 - 48 wt%) and HHV (18 - 20 MJ kg), and decreased N (∼2 wt%), S (<0.3 wt%) and ash (<15 wt%) content. A high GPW ratio (>50 wt%) during co-HTC resulted in a hydrochar similar to that obtained from GPW. The co-HTC increased nutrient migration to the process water, which allowed the precipitation of salt with high P (7.8 wt%) and negligible heavy metal content. Anaerobic digestion of co-HTC process water allowed high organic matter removal (up to 65%), and methane production (315 - 325 mL CH gCOD). Gross energy recovery by HTC and anaerobic digestion was 5 - 6-fold higher than anaerobic treatment of feedstocks. Therefore, co-HTC of SM and GPW with a ratio > 50% GPW proved to be a suitable approach to valorize and manage SM and obtain value-added products (hydrochar, mineral fertilizer and methane).

摘要

共水热碳化(co-HT)是提高低质废物水热碳化(HTC)的一种很有前途的策略。猪粪(SM)中 N(2.9wt%)、S(0.7wt%)和灰分(22.6wt%)含量高,C(35.6wt%)和高位热值(HHV;14.3MJkg)低,导致水热炭作为固体燃料的特性不佳。SM 和园林和公园废物(GPW)的共 HTC 改善了水热炭的特性(C 含量(43-48wt%)和 HHV(18-20MJkg),降低了 N(约 2wt%)、S(<0.3wt%)和灰分(<15wt%)含量。在共 HTC 过程中,较高的 GPW 比例(>50wt%)导致水热炭类似于 GPW 获得的水热炭。共 HTC 增加了养分向工艺水中的迁移,从而允许高 P(7.8wt%)和痕量重金属含量的盐沉淀。共 HTC 工艺水的厌氧消化允许高达 65%的有机物去除率,并产生 315-325mLCHgCOD 的甲烷。通过 HTC 和厌氧消化进行的总能量回收比原料的厌氧处理高出 5-6 倍。因此,SM 和 GPW 的共 HTC,其 GPW 比例>50%,被证明是一种有价值的利用和管理 SM 并获得增值产品(水热炭、矿物肥料和甲烷)的合适方法。

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