Zhang Zhicheng, Zhou Wanglin, Wang Tianlei, Gu Zhenbin, Zhu Yongfan, Liu Zhengkun, Wu Zhentao, Zhang Guangru, Jin Wanqin
State Key Laboratory of Materials-Oriented Chemical Engineering, College of Chemical Engineering, Nanjing Tech University, 30 Puzhu Road(S), Nanjing 211816, China.
Energy and Bioproducts Research Institute (EBRI), Aston University, Birmingham B4 7ET, UK.
Membranes (Basel). 2023 Jun 25;13(7):621. doi: 10.3390/membranes13070621.
Ion-conducting ceramic membranes, such as mixed oxygen ionic and electronic conducting (MIEC) membranes and mixed proton-electron conducting (MPEC) membranes, have the potential for absolute selectivity for specific gases at high temperatures. By utilizing these membranes in membrane reactors, it is possible to combine reaction and separation processes into one unit, leading to a reduction in by-product formation and enabling the use of thermal effects to achieve efficient and sustainable chemical production. As a result, membrane reactors show great promise in the production of various chemicals and fuels. This paper provides an overview of recent developments in dense ceramic catalytic membrane reactors and their potential for chemical production. This review covers different types of membrane reactors and their principles, advantages, disadvantages, and key issues. The paper also discusses the configuration and design of catalytic membrane reactors. Finally, the paper offers insights into the challenges of scaling up membrane reactors from experimental stages to practical applications.
离子传导陶瓷膜,如混合氧离子与电子传导(MIEC)膜以及混合质子 - 电子传导(MPEC)膜,在高温下对特定气体具有绝对选择性的潜力。通过在膜反应器中使用这些膜,有可能将反应和分离过程整合到一个单元中,从而减少副产物的形成,并利用热效应实现高效且可持续的化学生产。因此,膜反应器在各种化学品和燃料的生产中显示出巨大的潜力。本文概述了致密陶瓷催化膜反应器的最新进展及其在化学生产中的潜力。这篇综述涵盖了不同类型的膜反应器及其原理、优点、缺点和关键问题。本文还讨论了催化膜反应器的配置和设计。最后,本文深入探讨了将膜反应器从实验阶段扩大到实际应用所面临的挑战。