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精炼油中 3-氯-1,2-丙二醇酯和缩水甘油酯的消减——综述。

Mitigation of 3-monochloropropane 1,2 diol ester and glycidyl ester in refined oil - A review.

机构信息

Research & Development Department, IOI Edible Oils Sdn. Bhd., KM 12, Sg. Mowtas, Jalan Jaya Chip, off Jalan Batu Sapi, Sandakan, Sabah, Malaysia; Chemical Engineering Programme, Faculty of Engineering, Universiti Malaysia Sabah, 88400 Kota Kinabalu, Sabah, Malaysia.

Research & Development Department, IOI Edible Oils Sdn. Bhd., KM 12, Sg. Mowtas, Jalan Jaya Chip, off Jalan Batu Sapi, Sandakan, Sabah, Malaysia.

出版信息

Food Chem. 2023 Dec 15;429:136913. doi: 10.1016/j.foodchem.2023.136913. Epub 2023 Jul 17.

Abstract

The 3-Monochloropropane-1, 2-diol ester (3-MCPDE) and glycidyl ester (GE) are formed at high processing temperatures with the presence of respective precursors. Both are potentially harmful to humans, causing adverse health impacts including kidney damage, reproductive problems, and increased risk of cancer. The presence of 3-MCPDE and GE in palm oil is of particular concern because of its widespread use by the food industry. There are a variety of methods for reducing 3-MCPDE and GE. For example, water washing eliminates mostly inorganic chlorides that, in turn, reduce the formation of 3-MCPDE. 3-MCPDE has also been reduced by up to 99% using combinations of methods and replacing stripping steam with alcohol-based media. Activated carbon, clay, antioxidants, potassium-based salts, and other post-refining steps have positively lowered GE, ranging from 10 to 99%. Several approaches have been successful in reducing these process contaminants without affecting other quality metrics.

摘要

3-氯-1,2-丙二醇酯(3-MCPDE)和缩水甘油酯(GE)在存在相应前体的情况下,于高温加工过程中形成。两者都可能对人体造成危害,导致包括肾脏损伤、生殖问题和癌症风险增加在内的不良健康影响。由于棕榈油在食品工业中的广泛使用,其中存在的 3-MCPDE 和 GE 尤其令人担忧。有多种方法可以减少 3-MCPDE 和 GE。例如,水洗可以去除大部分无机氯化物,从而减少 3-MCPDE 的形成。通过组合使用方法并用基于酒精的介质代替汽提蒸汽,3-MCPDE 的含量也降低了 99%。活性炭、粘土、抗氧化剂、钾基盐和其他精炼后步骤已成功将 GE 降低 10%至 99%,效果显著。几种方法已成功降低了这些加工污染物,而不会影响其他质量指标。

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