Porous Rod-like NiTiO-BiOBr Heterojunctions with Highly Improved Visible-Light Photocatalytic Performance.

NiTiO-BiOBr heterostructured photocatalysts were constructed via precipitation, calcination and hydrothermal treatments. Various characterizations demonstrated that BiOBr nanosheets were decorated on NiTiO nanoparticals, forming porous rod-like heterojunctions. Compared with independent NiTiO and BiOBr, the composites with optimal BiOBr content presented highly improved visible-light photocatalytic efficiency. The degradation rates of Rhodamine B (RhB) and tetracycline (TC) reached 96.6% in 1.5 h (100% in 2 h) and 73.5% in 3 h, which are 6.61 and 1.53 times those of NiTiO, respectively. The result is an improved photocatalytic behavior from the formation of heterojunctions with a large interface area, which significantly promoted the separation of photogenerated carriers and strengthened the visible-light absorption. Based on the free radical capture experiments and band position analysis, the photodegradation mechanism of type-II heterojunction was deduced. This study provides a new way to fabricate highly efficient NiTiO-based photocatalysts for degrading certain organics.