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基于淀粉的高分子材料作为可持续水处理的先进吸附剂:现状、挑战与未来展望

Starch-Based Polymer Materials as Advanced Adsorbents for Sustainable Water Treatment: Current Status, Challenges, and Future Perspectives.

作者信息

Khoo Pui San, Ilyas R A, Uda M N A, Hassan Shukur Abu, Nordin A H, Norfarhana A S, Ab Hamid N H, Rani M S A, Abral Hairul, Norrrahim M N F, Knight V F, Lee Chuan Li, Rafiqah S Ayu

机构信息

Centre for Advanced Composite Materials, Universiti Teknologi Malaysia, Skudai 81310, Johor, Malaysia.

Faculty of Chemical and Energy Engineering, Universiti Teknologi Malaysia, Skudai 81310, Johor, Malaysia.

出版信息

Polymers (Basel). 2023 Jul 21;15(14):3114. doi: 10.3390/polym15143114.

Abstract

Over the past three decades, chemical and biological water contamination has become a major concern, particularly in the industrialized world. Heavy metals, aromatic compounds, and dyes are among the harmful substances that contribute to water pollution, which jeopardies the human health. For this reason, it is of the utmost importance to locate methods for the cleanup of wastewater that are not genuinely effective. Owing to its non-toxicity, biodegradability, and biocompatibility, starch is a naturally occurring polysaccharide that scientists are looking into as a possible environmentally friendly material for sustainable water remediation. Starch could exhibit significant adsorption capabilities towards pollutants with the substitution of amide, amino, carboxyl, and other functional groups for hydroxyl groups. Starch derivatives may effectively remove contaminants such as oil, organic solvents, pesticides, heavy metals, dyes, and pharmaceutical pollutants by employing adsorption techniques at a rate greater than 90%. The maximal adsorption capacities of starch-based adsorbents for oil and organic solvents, pesticides, heavy metal ions, dyes, and pharmaceuticals are 13,000, 66, 2000, 25,000, and 782 mg/g, respectively. Although starch-based adsorbents have demonstrated a promising future for environmental wastewater treatment, additional research is required to optimize the technique before the starch-based adsorbent can be used in large-scale in situ wastewater treatment.

摘要

在过去三十年中,化学和生物水污染已成为一个主要问题,尤其是在工业化国家。重金属、芳香族化合物和染料是导致水污染的有害物质,这危及人类健康。因此,找到真正有效的废水净化方法至关重要。由于淀粉具有无毒、可生物降解和生物相容性,它是一种天然存在的多糖,科学家们正在研究将其作为一种可能的环境友好型材料用于可持续的水修复。通过用酰胺基、氨基、羧基和其他官能团取代羟基,淀粉对污染物可能表现出显著的吸附能力。淀粉衍生物通过采用吸附技术可以有效去除油、有机溶剂、农药、重金属、染料和药物污染物等,去除率大于90%。淀粉基吸附剂对油和有机溶剂、农药、重金属离子、染料和药物的最大吸附容量分别为13000、66、2000、25000和782 mg/g。尽管淀粉基吸附剂在环境废水处理方面已展现出光明的前景,但在淀粉基吸附剂能够大规模用于原位废水处理之前,还需要进一步研究以优化该技术。

https://cdn.ncbi.nlm.nih.gov/pmc/blobs/80ed/10385024/b28a9b408466/polymers-15-03114-g001a.jpg

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