Zhang Shuting, Tian Fuqiang, Liang Jieyi, Cao Jinmei, Xing Zhaoliang
School of Electrical Engineering, Beijing Jiaotong University, Beijing 100044, China.
State Key Laboratory of Advanced Power Transmission Technology, Beijing 102209, China.
Polymers (Basel). 2023 Jul 22;15(14):3123. doi: 10.3390/polym15143123.
The insulating properties of polypropylene (PP) film play a very important role in the operating status of direct current (DC) support capacitors. Charging and discharging currents in PP film under high DC electric fields and temperatures correspond to charge transportation and accumulation, which significantly influence the electrical insulating properties of PP. In this paper, we have comprehensively studied the dependence of charging/discharging currents in PP film on time, electric field (150-670 kV/mm), and temperature (40-120 °C). The results showed that the charging current increased by almost an order of magnitude from 150 kV/mm to 670 kV/mm and exhibits a steep increase with temperature above 80 °C. The discharging currents are about 10 times less than the corresponding charging currents. Carrier mobility varies little with the electric field and becomes slightly larger with an increase in temperature. The quantity of the accumulated charges was calculated by the integral of the charging and discharging current differentials and showed a significant increase with the electric field and temperature. The corresponding electric field distortion becomes larger above 80 °C compared to 20-60 °C. Both electric field and temperature have an important effect on PP film and capacitors based on charge transport and accumulation and their electric field distortion. This study is innovative in that it combines the operating status of DC support capacitors with traditional methods to research synthetically charged transport mechanisms of PP film. The findings are meaningful for understanding the insulation failure mechanisms of PP film and capacitors under complex stresses.
聚丙烯(PP)薄膜的绝缘性能在直流(DC)支撑电容器的运行状态中起着非常重要的作用。在高直流电场和温度下,PP薄膜中的充放电电流对应着电荷的传输和积累,这对PP的电绝缘性能有显著影响。在本文中,我们全面研究了PP薄膜中充放电电流对时间、电场(150 - 670 kV/mm)和温度(40 - 120 °C)的依赖性。结果表明,充电电流从150 kV/mm到670 kV/mm几乎增加了一个数量级,并且在温度高于80 °C时呈现出急剧增加。放电电流约为相应充电电流的十分之一。载流子迁移率随电场变化不大,随温度升高略有增大。通过对充放电电流微分进行积分计算出积累电荷量,结果表明其随电场和温度显著增加。与20 - 60 °C相比,在80 °C以上相应的电场畸变变得更大。电场和温度都基于电荷传输、积累及其电场畸变对PP薄膜和电容器有重要影响。本研究的创新之处在于将直流支撑电容器的运行状态与传统方法相结合,综合研究PP薄膜的电荷传输机制。这些发现对于理解PP薄膜和电容器在复杂应力下的绝缘失效机制具有重要意义。