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环境催化剂的研究重点是晶格氧，用于分解有害有机化合物。

Environmental catalysts advance focused on lattice oxygen for the decomposition of harmful organic compounds.

机构信息

Department of Applied Chemistry, Faculty of Engineering, Osaka University.

出版信息

Proc Jpn Acad Ser B Phys Biol Sci. 2023;99(7):198-212. doi: 10.2183/pjab.99.013.

DOI:10.2183/pjab.99.013
PMID:37518009
原文链接:https://pmc.ncbi.nlm.nih.gov/articles/PMC10700014/
Abstract

The recent industrial growth has made our lives more comfortable; however, it has led to an increase in the concentration of harmful compounds, such as carbon monoxide, volatile organic compounds (e.g., toluene), and phenolic compounds (e.g., phenol and cresol), in the environment. Catalytic oxidation using environmental catalysts is an important method for the removal of harmful compounds. To date, novel environmental catalysts have been developed from unique concepts based on solid-state ionics. In particular, the oxygen supply ability of a promoter can supply active oxygen from inside the lattice to the catalytically active site. Our catalysts exhibited high activity for the oxidation of harmful chemicals under moderate conditions in both the gaseous and liquid phases compared to conventional catalysts. This short review article describes our concepts of material design and our novel catalysts (ceria-zirconia (CeO-ZrO), apatite-type lanthanum silicate (LaSiO), and lanthanum oxyfluoride (LaOF) based catalysts).

摘要

近年来的工业增长使我们的生活更加舒适；然而，这也导致环境中有害化合物（如一氧化碳、挥发性有机化合物（如甲苯）和酚类化合物（如苯酚和甲酚））的浓度增加。使用环境催化剂进行催化氧化是去除有害化合物的一种重要方法。迄今为止，新型环境催化剂是基于固态离子学的独特概念开发的。特别是，促进剂的供氧能力可以从晶格内部向催化活性位提供活性氧。与传统催化剂相比，我们的催化剂在气相和液相中均表现出在温和条件下氧化有害化学品的高活性。本文简要综述了我们的材料设计概念和新型催化剂（氧化铈-氧化锆（CeO-ZrO）、磷灰石型硅酸镧（LaSiO）和氟化镧（LaOF）基催化剂）。

https://cdn.ncbi.nlm.nih.gov/pmc/blobs/82fa/10700014/92e5eadac29f/pjab-99-198-g010.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/82fa/10700014/ab212feb9854/pjab-99-198-g001.jpg
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https://cdn.ncbi.nlm.nih.gov/pmc/blobs/82fa/10700014/c2c8c8aaf123/pjab-99-198-g004.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/82fa/10700014/a0e0f3e1bdbd/pjab-99-198-g005.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/82fa/10700014/3a33f2b537ec/pjab-99-198-g006.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/82fa/10700014/2ff909b573a2/pjab-99-198-g007.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/82fa/10700014/f2f07a878cfb/pjab-99-198-g008.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/82fa/10700014/47be25b8909e/pjab-99-198-g009.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/82fa/10700014/92e5eadac29f/pjab-99-198-g010.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/82fa/10700014/ab212feb9854/pjab-99-198-g001.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/82fa/10700014/f13f5d936c39/pjab-99-198-g002.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/82fa/10700014/cfa0da3d9e9b/pjab-99-198-g003.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/82fa/10700014/c2c8c8aaf123/pjab-99-198-g004.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/82fa/10700014/a0e0f3e1bdbd/pjab-99-198-g005.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/82fa/10700014/3a33f2b537ec/pjab-99-198-g006.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/82fa/10700014/2ff909b573a2/pjab-99-198-g007.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/82fa/10700014/f2f07a878cfb/pjab-99-198-g008.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/82fa/10700014/47be25b8909e/pjab-99-198-g009.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/82fa/10700014/92e5eadac29f/pjab-99-198-g010.jpg

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本文引用的文献

1
Recent Advances in the Catalytic Oxidation of Volatile Organic Compounds: A Review Based on Pollutant Sorts and Sources.挥发性有机化合物催化氧化的最新进展：基于污染物种类和来源的综述。
Chem Rev. 2019 Apr 10;119(7):4471-4568. doi: 10.1021/acs.chemrev.8b00408. Epub 2019 Feb 27.
2
Iron Based Catalysts Used in Water Treatment Assisted by Ultrasound: A Mini Review.超声辅助水处理中使用的铁基催化剂：一篇综述
Front Chem. 2018 Feb 2;6:12. doi: 10.3389/fchem.2018.00012. eCollection 2018.
3
Novel Catalysts for Methane Combustion Based on Cobalt-Doped Lanthanum Silicates Having an Apatite-type Structure.
基于具有磷灰石结构的钴掺杂镧硅酸盐的甲烷燃烧新型催化剂。
ACS Appl Mater Interfaces. 2017 Nov 22;9(46):40344-40350. doi: 10.1021/acsami.7b14069. Epub 2017 Nov 7.
4
Fundamentals and Catalytic Applications of CeO2-Based Materials.基于 CeO2 的材料的基础原理及催化应用。
Chem Rev. 2016 May 25;116(10):5987-6041. doi: 10.1021/acs.chemrev.5b00603. Epub 2016 Apr 27.
5
Unprecedented Perovskite Oxyfluoride Membranes with High-Efficiency Oxygen Ion Transport Paths for Low-Temperature Oxygen Permeation.具有高效氧离子输运通道的低温氧渗透用无定形钙钛矿氧氟化物膜
Adv Mater. 2016 May;28(18):3511-5. doi: 10.1002/adma.201505959. Epub 2016 Mar 10.
6
Structural refinement of the RT LaOF phases by coupling powder X-Ray diffraction, (19)F and (139)La solid state NMR and DFT calculations of the NMR parameters.通过结合粉末X射线衍射、（19）F和（139）La固态核磁共振以及核磁共振参数的密度泛函理论计算对RT LaOF相进行结构精修。
Dalton Trans. 2015 Dec 21;44(47):20675-84. doi: 10.1039/c5dt04028k. Epub 2015 Nov 13.
7
Importance of platinum particle size for complete oxidation of toluene over Pt/ZSM-5 catalysts.铂颗粒尺寸对Pt/ZSM-5催化剂上甲苯完全氧化的重要性。
Chem Commun (Camb). 2015 Apr 7;51(27):5936-8. doi: 10.1039/c4cc09383f. Epub 2015 Mar 4.
8
Carbon monoxide oxidation at room temperature on Pt/CeO2-ZrO2-Bi2O3 catalysts.Pt/CeO2-ZrO2-Bi2O3 催化剂上室温下的一氧化碳氧化。
Chem Commun (Camb). 2011 Oct 21;47(39):11032-4. doi: 10.1039/c1cc12348c. Epub 2011 Sep 12.
9
Heterogeneous catalytic wet air oxidation of refractory organic pollutants in industrial wastewaters: a review.工业废水中难处理有机污染物的多相湿式催化氧化：综述。
J Hazard Mater. 2011 Feb 15;186(1):16-34. doi: 10.1016/j.jhazmat.2010.11.011. Epub 2010 Nov 11.
10
Total oxidation of toluene on Pt/CeO2-ZrO2-Bi2O3/gamma-Al2O3 catalysts prepared in the presence of polyvinyl pyrrolidone.在聚乙烯吡咯烷酮存在下制备的 Pt/CeO2-ZrO2-Bi2O3/γ-Al2O3 催化剂上甲苯的完全氧化。
J Hazard Mater. 2010 Apr 15;176(1-3):1106-9. doi: 10.1016/j.jhazmat.2009.11.108. Epub 2009 Nov 26.