Zhu Lizhao, Kinjo Rei
School of Chemistry, Chemical Engineering and Biotechnology, Nanyang Technological University, Nanyang Link 21, Singapore 637371, Singapore.
Chem Soc Rev. 2023 Aug 14;52(16):5563-5606. doi: 10.1039/d3cs00290j.
Since the seminal discovery of phenyl azide by Grieß in 1864, a variety of organic azides (R-N) have been developed and extensively studied. The amenability of azides to a number of reactions has expanded their utility as building blocks not only in organic synthesis but also in bioorthogonal chemistry and materials science. Over the decades, it has been demonstrated that the reactions of main group compounds with azides lead to diverse N-containing main group molecules. In view of the pronounced progress in this area, this review summarizes the reactions of main group compounds with azides, emphatically introducing their reaction patterns and mechanisms. The reactions of forming inorganic nitrogen species are not included in this review.
自1864年格里斯发现苯叠氮以来，已开发并广泛研究了多种有机叠氮化物（R-N）。叠氮化物对多种反应的适应性不仅扩大了它们作为有机合成、生物正交化学和材料科学中构建单元的用途。几十年来，已经证明主族化合物与叠氮化物的反应会产生各种含氮主族分子。鉴于该领域取得的显著进展，本综述总结了主族化合物与叠氮化物的反应，着重介绍了它们的反应模式和机理。本综述不包括形成无机氮物种的反应。
