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采用混合技术的新型喷泉反应器设计,用于利用高级氧化工艺进行污染降解及建模评估。

Design of a new fountain reactor for contamination degradation using advanced oxidation processes with hybrid techniques and modeling evaluation.

机构信息

Department of Chemical Engineering, School of Material Engineering and Advanced Processes, Amirkabir University of Technology, Tehran, 15875-4413, Iran.

Department of Chemical and Biological Engineering, The University of British Columbia, 2360, East Mall, Vancouver, BC, V6T 1Z3, Canada.

出版信息

Environ Sci Pollut Res Int. 2023 Sep;30(41):94097-94111. doi: 10.1007/s11356-023-28491-z. Epub 2023 Aug 1.

DOI:10.1007/s11356-023-28491-z
PMID:37525080
Abstract

Due to the water and energy crises, wastewater treatment systems that are more energy efficient and capable of large volume degradation are a priority. Photochemical decomposition methods have a significant impact on pollutant treatment. The use of these methods in conjunction with a novel designed reactor and hybridization processes can result in considerable treatment results. This research used a fountain system in a UV/HO process to generate a belt-type liquid film with a low thickness and high mixing to remove methyl orange as a model pollutant. The flow rate, HO concentration, temperature, and UV intensity were the parameters evaluated in this series of tests. After 90 minutes under optimum conditions, the maximum degradation of methyl orange was 99.73 percent. The efficiency of the purification process was increased to 99 percent in 75 minutes by using the optimum state of hybridization of UV/US/HO processes. Two deep neural network models and a pseudo-first-order kinetic model were created to fit the experimental data. The results reveal a good fit between the experimental data and the model prediction. The discovered synergistic factor (1.168) and energy yield (2.65 g/kWh) demonstrated the high efficiency of the hybridization process and the outstanding function of the designed system, respectively.

摘要

由于水和能源危机,更节能且能够大量降解的废水处理系统是当务之急。光化学分解方法对污染物处理有重大影响。将这些方法与新型设计的反应器和杂交工艺结合使用,可以取得相当好的处理效果。本研究在 UV/HO 工艺中使用喷泉系统生成厚度低、混合度高的带状液膜,以去除甲基橙作为模型污染物。本系列试验评估了流速、HO 浓度、温度和 UV 强度等参数。在最佳条件下反应 90 分钟后,甲基橙的最大降解率达到 99.73%。通过使用 UV/US/HO 过程的最佳杂交状态,将净化过程的效率提高到 75 分钟内达到 99%。建立了两个深度神经网络模型和一个拟一级动力学模型来拟合实验数据。结果表明,实验数据与模型预测之间具有良好的拟合度。发现的协同因子(1.168)和能量产率(2.65 g/kWh)分别表明了杂交工艺的高效率和设计系统的卓越功能。

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