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预搅拌时间对浮选技术中粉煤灰脱碳的影响

Effect of Prestirring Time on Carbon Removal from Coal Fly Ash in the Flotation Technology.

作者信息

Liu Ke, Jiang Jinming, Takasu Koji, Wan Jian, Gao Weijun

机构信息

Faculty of Environmental Engineering, The University of Kitakyushu, 1-1 Hibikino Wakamatsu, Kitakyushu, Fukuoka 8080135, Japan.

Innovation Institute for Sustainable Maritime Architecture Research and Technology (iSMART), Qingdao University of Technology, Qingdao 266033, China.

出版信息

ACS Omega. 2023 Jul 23;8(30):27794-27801. doi: 10.1021/acsomega.3c04121. eCollection 2023 Aug 1.

Abstract

Coal fly ash (CFA) is one of the industrial byproducts of burning coal for energy production and has unburned carbon, which negatively affects its full potential use. The flotation technology can be effective in separating unburned carbon from CFA, and the prestirring time is crucial for the ideal initial conditions during the flotation process. To find the suitable prestirring time, eight prestirring times, including 0, 1, 2, 3, 4, 5, 6, and 7 min, were selected in this paper, followed by flotation of CFA after prestirring. Parameters such as loss on ignition (LOI), the removal rate of unburned carbon (RUC), contact angle, and particle size volume fraction were used to assess the effect of prestirring time on flotation results. The results showed that the prestirring time significantly affects the CFA flotation performance. As the prestirring time increased, the LOI of CFA first decreased and then increased, and the contact angle showed the opposite trend. Besides, the prestirring time of over 2 min positively affected the fineness of the tailings. Overall, the prestirring time of 3 min had the most significant carbon removal effect, obtaining an LOI of tailings of 0.96%, a yield of 74.56%, an RUC of 72.70%, and a volume fraction less than 45 μm of 36.65%. This study provides theoretical support for improving stirring efficiency and saving flotation costs in industrial applications and is conducive to the recycling of CFA resources.

摘要

煤粉煤灰(CFA)是煤炭燃烧用于能源生产的工业副产品之一,含有未燃尽碳,这对其充分利用产生负面影响。浮选技术可有效从CFA中分离未燃尽碳,预搅拌时间对浮选过程中的理想初始条件至关重要。为找到合适的预搅拌时间,本文选取了0、1、2、3、4、5、6和7分钟这八个预搅拌时间,然后对CFA进行预搅拌后浮选。采用烧失量(LOI)、未燃尽碳去除率(RUC)、接触角和粒度体积分数等参数评估预搅拌时间对浮选结果的影响。结果表明,预搅拌时间显著影响CFA的浮选性能。随着预搅拌时间增加,CFA的LOI先降低后升高,接触角则呈相反趋势。此外,超过2分钟的预搅拌时间对尾矿细度有积极影响。总体而言,3分钟的预搅拌时间具有最显著的除碳效果,尾矿的LOI为0.96%,产率为74.56%,RUC为72.70%,小于45μm的体积分数为36.65%。本研究为工业应用中提高搅拌效率和节约浮选成本提供了理论支持,有利于CFA资源的回收利用。

https://cdn.ncbi.nlm.nih.gov/pmc/blobs/b51b/10398837/cdc4d7686f8b/ao3c04121_0002.jpg

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