Liu Fangjun, Shen Chenxi, You Feng, Zhao Wufan, Deng Caoting, Jiang Xueliang
Key Laboratory for Green Chemical Process of Ministry of Education, School of Materials Science and Engineering, Wuhan Institute of Technology, Wuhan, 430073, P. R. China.
Macromol Rapid Commun. 2023 Oct;44(20):e2300344. doi: 10.1002/marc.202300344. Epub 2023 Aug 13.
High-performance polypropylene (PP) foam is a vital polymer product in industrial areas. However, the poor melt strength of ordinary PP homopolymer limits its foaming molding. In this work, high melt strength polypropylene (HMSPP) is prepared by using styrene (St) and tripropylene glycol diacrylate (TPGDA) as comonomers, and then PP foams are prepared by mold foaming method. The results show that adding St in the grafting process of TPGDA will obviously improve the melt strength of the PP matrix, and its melt strength (28 184 Pa.s) is 7.4 times higher than that of pure PP. HMSPP foam has more regular and uniform cells and higher cell density, which significantly improves the sound and thermal insulation properties of PP foam. Compared with pure PP foam, the average sound transmission loss (52.9 dB) of HMSPP foam with a low foaming ratio increased by 64%, and the thermal conductivity (0.0867 W mK ) decreased by 46%. Therefore, the obtained HMSPP foam can be used in sound insulation or thermal insulation area. This work provides an available route for the high-performance utilization of PP foam.
高性能聚丙烯(PP)泡沫是工业领域中一种重要的聚合物产品。然而,普通PP均聚物的熔体强度较差,限制了其发泡成型。在本工作中,以苯乙烯(St)和三丙二醇二丙烯酸酯(TPGDA)作为共聚单体制备了高熔体强度聚丙烯(HMSPP),然后采用模塑发泡法制备了PP泡沫。结果表明,在TPGDA的接枝过程中加入St会显著提高PP基体的熔体强度,其熔体强度(28184Pa·s)比纯PP高7.4倍。HMSPP泡沫具有更规则、均匀的泡孔和更高的泡孔密度,显著提高了PP泡沫的隔音和隔热性能。与纯PP泡沫相比,低发泡倍率的HMSPP泡沫的平均传声损失(52.9dB)提高了64%,热导率(0.0867W·mK)降低了46%。因此,所制备的HMSPP泡沫可用于隔音或隔热领域。本工作为PP泡沫的高性能利用提供了一条可行途径。