Salinas Gerardo, Kuhn Alexander, Arnaboldi Serena
Université Bordeaux, CNRS, Bordeaux INP, ISM, UMR 5255, F-33607 Pessac, France.
Dipartimento di Chimica, Universita degli Studi di Milano, 20133 Milano, Italy.
J Phys Chem C Nanomater Interfaces. 2023 Jul 21;127(30):14704-14710. doi: 10.1021/acs.jpcc.3c01597. eCollection 2023 Aug 3.
Rotation is an interesting type of motion that is currently involved in many technological applications. In this frame, different and sophisticated external stimuli to induce rotation have been developed. In this work, we have designed a simple and original self-propelled bimetallic Janus rotor powered by the synergy between a spontaneous electric and ionic current, produced by two coupled redox reactions, and a magnetic field, placed orthogonal to the surface of the device. Such a combination induces a magnetohydrodynamic vortex at each extremity of the rotor arm, which generates an overall driving force able to propel the rotor. Furthermore, the motion of the self-polarized object can be controlled by the direction of the spontaneous electric current or the orientation of the external magnetic field, resulting in a predictable clockwise or anticlockwise motion. In addition, these devices exhibit directional corkscrew-type displacement, when representing their displacement as a function of time, producing time-space specular behavior. The concept can be used to design alternative self-mixing systems for a variety of (micro)fluidic equipment.
旋转是一种有趣的运动类型,目前在许多技术应用中都有涉及。在这种情况下,已经开发出了不同的、复杂的外部刺激来诱导旋转。在这项工作中,我们设计了一种简单且独特的自驱动双金属Janus转子,它由两个耦合氧化还原反应产生的自发电流和离子电流与垂直于设备表面放置的磁场之间的协同作用提供动力。这种组合在转子臂的每个末端诱导出一个磁流体动力学涡旋,从而产生一个能够推动转子的整体驱动力。此外,自极化物体的运动可以通过自发电流的方向或外部磁场的方向来控制,从而产生可预测的顺时针或逆时针运动。此外,当将这些设备的位移表示为时间的函数时,它们会表现出定向螺旋式位移,产生时空镜面行为。这一概念可用于为各种(微)流体设备设计替代的自混合系统。