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冻融与硫酸盐侵蚀耦合作用下新型灌浆材料的性能

Performance of a New Grouting Material under the Coupling Effects of Freeze-Thaw and Sulfate Erosion.

作者信息

Ma Qinyong, Li Biao

机构信息

School of Civil Engineering and Architecture, Anhui University of Science and Technology, Huainan 232001, China.

Engineering Research Center of Underground Mine Construction, Ministry of Education, Anhui University of Science and Technology, Huainan 232001, China.

出版信息

Materials (Basel). 2023 Aug 3;16(15):5448. doi: 10.3390/ma16155448.

Abstract

In order to study the performance of a new cement-based grouting material under the coupling of freeze-thaw cycle and sulfate erosion, tests related to the performance of the new grouting material were designed and carried out to analyze the damage mechanism of the material under the coupling of freezing and thawing and NaSO solution by testing the mass change, relative dynamic elastic modulus, compressive strength loss and mineralogical and microstructural properties of the new grouting material. The test results show that with the increase in the number of freeze-thaw cycles, the mass loss and compressive strength loss of the specimens in 15% NaSO solution gradually increased, and the relative dynamic elastic modulus showed a decreasing trend. When the freeze-thaw cycle number was 30, the mass loss rate, compressive strength loss rate and relative dynamic elastic modulus of the specimens in NaSO solution were 4.17%, 24.59% and 84.3%, respectively, which showed better erosion and frost durability. Mineralogical and microstructural analysis showed that SO in solution led to the decomposition of the C-S-H gel and the formation of CaSO•2HO inside the specimen, and the internal deterioration was exacerbated by the widening of the crack width being aggravated, suggesting that the rate of material deterioration under the coupling of the two factors increased.

摘要

为研究一种新型水泥基灌浆材料在冻融循环与硫酸盐侵蚀耦合作用下的性能,设计并开展了与该新型灌浆材料性能相关的试验,通过测试新型灌浆材料的质量变化、相对动弹模量、抗压强度损失以及矿物学和微观结构性能,分析材料在冻融与硫酸钠溶液耦合作用下的损伤机理。试验结果表明,随着冻融循环次数的增加,15%硫酸钠溶液中试件的质量损失和抗压强度损失逐渐增大,相对动弹模量呈下降趋势。当冻融循环次数为30次时,硫酸钠溶液中试件的质量损失率、抗压强度损失率和相对动弹模量分别为4.17%、24.59%和84.3%,表现出较好的抗侵蚀和抗冻耐久性。矿物学和微观结构分析表明,溶液中的硫酸根导致试件内部C-S-H凝胶分解并生成CaSO•2HO,且裂纹宽度增大加剧了内部劣化,表明两种因素耦合作用下材料劣化速率加快。

https://cdn.ncbi.nlm.nih.gov/pmc/blobs/9507/10420313/859b37fddf5c/materials-16-05448-g001.jpg

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