• 文献检索
  • 文档翻译
  • 深度研究
  • 学术资讯
  • Suppr Zotero 插件Zotero 插件
  • 邀请有礼
  • 套餐&价格
  • 历史记录
应用&插件
Suppr Zotero 插件Zotero 插件浏览器插件Mac 客户端Windows 客户端微信小程序
定价
高级版会员购买积分包购买API积分包
服务
文献检索文档翻译深度研究API 文档MCP 服务
关于我们
关于 Suppr公司介绍联系我们用户协议隐私条款
关注我们

Suppr 超能文献

核心技术专利：CN118964589B侵权必究
粤ICP备2023148730 号-1Suppr @ 2026

文献检索

告别复杂PubMed语法，用中文像聊天一样搜索，搜遍4000万医学文献。AI智能推荐，让科研检索更轻松。

立即免费搜索

文件翻译

保留排版，准确专业，支持PDF/Word/PPT等文件格式，支持 12+语言互译。

免费翻译文档

深度研究

AI帮你快速写综述，25分钟生成高质量综述，智能提取关键信息，辅助科研写作。

立即免费体验

使用功能化硫代水杨酸基离子液体去除锰：水过滤系统应用

Manganese Removal Using Functionalised Thiosalicylate-Based Ionic Liquid: Water Filtration System Application.

作者信息

Basirun Ain Aqilah, Karim Wan Azlina Wan Ab, Wei Ng Cheah, Wu Jiquan, Wilfred Cecilia Devi

机构信息

Centre of Research in Ionic Liquids (CORIL), Institute of Contaminant Management (ICM), Universiti Teknologi PETRONAS, Seri Iskandar 32610, Perak, Malaysia.

Faculty of Engineering, Universiti Putra Malaysia (UPM), Serdang 43400, Selangor, Malaysia.

出版信息

Molecules. 2023 Jul 31;28(15):5777. doi: 10.3390/molecules28155777.

DOI:10.3390/molecules28155777
PMID:37570745
原文链接:https://pmc.ncbi.nlm.nih.gov/articles/PMC10420996/
Abstract

Aiming at the generation of new functionalised thiosalicylate-based ionic liquids, a polymeric hydrogel consisting of 1-hexylimidazole propionitrile thiosalicylate [HIMP][TS], with a solid biomaterial support based on polyvinyl alcohol (PVA)-alginate beads, was produced. This study aimed to develop a treatment method for removing manganese (Mn) heavy metal from industrial wastewater, which is known to be toxic and harmful towards the environment and human health. The method utilised an adsorption-based approach with an alginate adsorbent that incorporated a functionalised thiosalicylate-based ionic liquid. The synthesised smooth round beads of PVA-alginate-[HIMP][TS] adsorbent were structurally characterised using Fourier transform infrared spectroscopy (FTIR) and field emission scanning electron microscopy (FESEM). The Mn concentration and removal efficiency were evaluated using atomic absorption spectroscopy (AAS). Three important parameters were evaluated: pH, adsorbent dosage, and contact time. During optimisation using the interactive factor design of experiments through the Box-Behnken model, the results showed that the system achieved a maximum Mn removal efficiency of 98.91% at an initial pH of 7.15, with a contact time of 60 min, using a bead dosage of 38.26 g/L. The beads were also tested in an available water filtration prototype system to illustrate their industrial application, and the performance showed a removal efficiency of 99.14% with 0 NTU total suspended solid (TSS) and 0.13 mg/L turbidity analysis. The recyclability of PVA-alginate-[HIMP][TS] beads using 0.5 M HCl resulted in four cycles with constant 99% Mn removal. The adsorption capacity of Mn was also determined in optimum conditions with 56 mg/g. Therefore, the alginate-thiosalicylate-based ionic liquid system is considered an effective and environmentally friendly method for removing Mn heavy metal due to the high removal efficiency achieved.

摘要

为了生成新型功能化硫代水杨酸基离子液体，制备了一种由1-己基咪唑丙腈硫代水杨酸盐[HIMP][TS]组成的聚合物水凝胶，并以基于聚乙烯醇（PVA）-海藻酸钠珠的固体生物材料为载体。本研究旨在开发一种从工业废水中去除锰（Mn）重金属的处理方法，已知锰对环境和人类健康有毒有害。该方法采用基于吸附的方法，使用含有功能化硫代水杨酸基离子液体的海藻酸盐吸附剂。使用傅里叶变换红外光谱（FTIR）和场发射扫描电子显微镜（FESEM）对合成的光滑圆形PVA-海藻酸钠-[HIMP][TS]吸附剂珠进行结构表征。使用原子吸收光谱法（AAS）评估锰浓度和去除效率。评估了三个重要参数：pH值、吸附剂用量和接触时间。在通过Box-Behnken模型使用交互式因子设计实验进行优化过程中，结果表明，该系统在初始pH值为7.15、接触时间为60分钟、珠用量为38.26 g/L的条件下，实现了98.91%的最大锰去除效率。还在一个可用的水过滤原型系统中对这些珠子进行了测试，以说明它们的工业应用，性能显示去除效率为99.14%，总悬浮固体（TSS）为0 NTU，浊度分析为0.13 mg/L。使用0.5 M HCl对PVA-海藻酸钠-[HIMP][TS]珠进行回收利用，可进行四个循环，锰去除率恒定为99%。在最佳条件下还测定了锰的吸附容量为56 mg/g。因此，基于海藻酸盐-硫代水杨酸的离子液体系统由于实现了高去除效率，被认为是一种有效且环保的去除锰重金属的方法。

https://cdn.ncbi.nlm.nih.gov/pmc/blobs/7a10/10420996/e6cff0d87e42/molecules-28-05777-g015.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/7a10/10420996/6b071d7ca067/molecules-28-05777-g001.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/7a10/10420996/0a601528f9ea/molecules-28-05777-g002.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/7a10/10420996/d19d4a85479f/molecules-28-05777-g003.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/7a10/10420996/f428ce728991/molecules-28-05777-g004.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/7a10/10420996/347aae147486/molecules-28-05777-g005.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/7a10/10420996/09736d41b5af/molecules-28-05777-g006.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/7a10/10420996/d0ebf7f02875/molecules-28-05777-g007.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/7a10/10420996/c5dcb5672e06/molecules-28-05777-g008.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/7a10/10420996/09b0f6a9a227/molecules-28-05777-g009.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/7a10/10420996/6907c7e3d76e/molecules-28-05777-g010.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/7a10/10420996/4ac9b298ec02/molecules-28-05777-g011.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/7a10/10420996/1ab9420992e0/molecules-28-05777-g012.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/7a10/10420996/7015fbac4d3b/molecules-28-05777-g013.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/7a10/10420996/0ad266f7809a/molecules-28-05777-g014.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/7a10/10420996/e6cff0d87e42/molecules-28-05777-g015.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/7a10/10420996/6b071d7ca067/molecules-28-05777-g001.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/7a10/10420996/0a601528f9ea/molecules-28-05777-g002.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/7a10/10420996/d19d4a85479f/molecules-28-05777-g003.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/7a10/10420996/f428ce728991/molecules-28-05777-g004.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/7a10/10420996/347aae147486/molecules-28-05777-g005.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/7a10/10420996/09736d41b5af/molecules-28-05777-g006.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/7a10/10420996/d0ebf7f02875/molecules-28-05777-g007.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/7a10/10420996/c5dcb5672e06/molecules-28-05777-g008.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/7a10/10420996/09b0f6a9a227/molecules-28-05777-g009.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/7a10/10420996/6907c7e3d76e/molecules-28-05777-g010.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/7a10/10420996/4ac9b298ec02/molecules-28-05777-g011.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/7a10/10420996/1ab9420992e0/molecules-28-05777-g012.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/7a10/10420996/7015fbac4d3b/molecules-28-05777-g013.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/7a10/10420996/0ad266f7809a/molecules-28-05777-g014.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/7a10/10420996/e6cff0d87e42/molecules-28-05777-g015.jpg

相似文献

1
Manganese Removal Using Functionalised Thiosalicylate-Based Ionic Liquid: Water Filtration System Application.使用功能化硫代水杨酸基离子液体去除锰：水过滤系统应用
Molecules. 2023 Jul 31;28(15):5777. doi: 10.3390/molecules28155777.
2
Synthesis and Characterization of Novel Thiosalicylate-based Solid-Supported Ionic Liquid for Removal of Pb(II) Ions from Aqueous Solution.新型基于硫代水杨酸的固载型离子液体的合成与表征及其对水溶液中 Pb(II)离子的去除。
Molecules. 2023 Jan 13;28(2):830. doi: 10.3390/molecules28020830.
3
Synthesis and Characterization of Biodegradable Poly(vinyl alcohol)-Chitosan/Cellulose Hydrogel Beads for Efficient Removal of Pb(II), Cd(II), Zn(II), and Co(II) from Water.用于高效去除水中Pb(II)、Cd(II)、Zn(II)和Co(II)的可生物降解聚乙烯醇-壳聚糖/纤维素水凝胶珠的合成与表征
Gels. 2023 Apr 13;9(4):328. doi: 10.3390/gels9040328.
4
Ionic Liquid Agar-Alginate Beads as a Sustainable Phenol Adsorbent.离子液体琼脂-海藻酸盐珠作为一种可持续的苯酚吸附剂。
Polymers (Basel). 2022 Feb 28;14(5):984. doi: 10.3390/polym14050984.
5
Clay-Alginate Beads Loaded with Ionic Liquids: Potential Adsorbents for the Efficient Extraction of Oil from Produced Water.负载离子液体的粘土-海藻酸钠珠粒：从采出水中高效提取油的潜在吸附剂。
Polymers (Basel). 2022 Oct 20;14(20):4440. doi: 10.3390/polym14204440.
6
Removal of lead from aqueous solution using electrospun nanofibers: preparation, characterization, adsorption isotherm, and kinetic study.采用静电纺丝纳米纤维从水溶液中去除铅：制备、表征、吸附等温线和动力学研究。
Anal Methods. 2022 Sep 15;14(35):3382-3396. doi: 10.1039/d2ay00691j.
7
Crosslinked chitosan/poly(vinyl alcohol) nanofibers functionalized by ionic liquid for heavy metal ions removal.离子液体功能化交联壳聚糖/聚乙烯醇纳米纤维用于重金属离子去除。
Int J Biol Macromol. 2022 Jan 15;195:132-141. doi: 10.1016/j.ijbiomac.2021.12.008. Epub 2021 Dec 10.
8
Preparation and characterization of immobilized [A336][MTBA] in PVA-alginate gel beads as novel solid-phase extractants for an efficient recovery of Hg (II) from aqueous solutions.制备并表征了固定在 PVA-海藻酸钠凝胶珠中的[A336][MTBA]作为新型固相萃取剂，用于从水溶液中高效回收 Hg(II)。
J Hazard Mater. 2011 Nov 30;196:201-9. doi: 10.1016/j.jhazmat.2011.09.018. Epub 2011 Sep 10.
9
Fabrication of nanofibers using sodium alginate and Poly(Vinyl alcohol) for the removal of Cd ions from aqueous solutions: adsorption mechanism, kinetics and thermodynamics.使用海藻酸钠和聚乙烯醇制备纳米纤维用于从水溶液中去除镉离子：吸附机理、动力学和热力学
Heliyon. 2019 Nov 29;5(11):e02941. doi: 10.1016/j.heliyon.2019.e02941. eCollection 2019 Nov.
10
Response surface methodology for optimization of methylene blue adsorption onto carboxymethyl cellulose-based hydrogel beads: adsorption kinetics, isotherm, thermodynamics and reusability studies.响应面法优化亚甲基蓝在羧甲基纤维素基水凝胶珠上的吸附：吸附动力学、等温线、热力学及可重复使用性研究
RSC Adv. 2019 Nov 20;9(65):37858-37869. doi: 10.1039/c9ra06450h. eCollection 2019 Nov 19.

引用本文的文献

1
Catalysis in Energy and the Environment: Opportunities and Challenges.能源与环境中的催化作用：机遇与挑战
Molecules. 2024 Apr 24;29(9):1932. doi: 10.3390/molecules29091932.
2
Biopolymeric Nanocomposites for Wastewater Remediation: An Overview on Recent Progress and Challenges.用于废水修复的生物聚合物纳米复合材料：最新进展与挑战概述
Polymers (Basel). 2024 Jan 21;16(2):294. doi: 10.3390/polym16020294.

本文引用的文献

1
Extraction of Gold Based on Ionic Liquid Immobilized in UiO-66: An Efficient and Reusable Way to Avoid IL Loss Caused by Ion Exchange in Solvent Extraction.基于 UiO-66 中固定化离子液体的金提取：一种有效且可重复使用的方法，可避免溶剂萃取中离子交换导致的 IL 损失。
Molecules. 2023 Feb 25;28(5):2165. doi: 10.3390/molecules28052165.
2
Synthesis and Characterization of Novel Thiosalicylate-based Solid-Supported Ionic Liquid for Removal of Pb(II) Ions from Aqueous Solution.新型基于硫代水杨酸的固载型离子液体的合成与表征及其对水溶液中 Pb(II)离子的去除。
Molecules. 2023 Jan 13;28(2):830. doi: 10.3390/molecules28020830.
3
Cross-Linked Ionic Liquid Polymer for the Effective Removal of Ionic Dyes from Aqueous Systems: Investigation of Kinetics and Adsorption Isotherms.
交联离子液体聚合物对水溶液中离子染料的有效去除：动力学和吸附等温线研究。
Molecules. 2022 Nov 11;27(22):7775. doi: 10.3390/molecules27227775.
4
Fabrication of Effective Nanohybrids Based on Organic Species, Polyvinyl Alcohol and Carbon Nanotubes in Addition to Nanolayers for Removing Heavy Metals from Water under Severe Conditions.基于有机物种、聚乙烯醇和碳纳米管以及纳米层制备高效纳米杂化物，用于在严苛条件下去除水中重金属。
Molecules. 2022 Aug 9;27(16):5054. doi: 10.3390/molecules27165054.
5
Environmentally Friendly Polyvinyl Alcohol-Alginate/Bentonite Semi-Interpenetrating Polymer Network Nanocomposite Hydrogel Beads as an Efficient Adsorbent for the Removal of Methylene Blue from Aqueous Solution.环境友好型聚乙烯醇-海藻酸盐/膨润土半互穿聚合物网络纳米复合水凝胶珠作为从水溶液中去除亚甲基蓝的高效吸附剂
Polymers (Basel). 2021 Nov 19;13(22):4000. doi: 10.3390/polym13224000.
6
Phase Transitions and Electrochemical Properties of Ionic Liquids and Ionic Liquid-Solvent Mixtures.离子液体及离子液体 - 溶剂混合物的相变与电化学性质
Molecules. 2021 Jun 16;26(12):3668. doi: 10.3390/molecules26123668.
7
Adsorption of emerging contaminants from water and wastewater by modified biochar: A review.改性生物炭对水和废水中新兴污染物的吸附：综述
Environ Pollut. 2021 Jan 6;273:116448. doi: 10.1016/j.envpol.2021.116448.
8
Evolution of adsorption process for manganese removal in water via agricultural waste adsorbents.通过农业废弃物吸附剂去除水中锰的吸附过程演变
Heliyon. 2020 Oct 1;6(9):e05049. doi: 10.1016/j.heliyon.2020.e05049. eCollection 2020 Sep.
9
Heavy metal pollution in the environment and their toxicological effects on humans.环境中的重金属污染及其对人类的毒理学影响。
Heliyon. 2020 Sep 8;6(9):e04691. doi: 10.1016/j.heliyon.2020.e04691. eCollection 2020 Sep.
10
Solubility and Selectivity Effects of the Anion on the Adsorption of Different Heavy Metal Ions onto Chitosan.阴离子对壳聚糖吸附不同重金属离子的溶解度和选择性的影响。
Molecules. 2020 May 27;25(11):2482. doi: 10.3390/molecules25112482.