Arifin Heni Radiani, Utaminingsih Fitriana, Djali Mohamad, Nurhadi Bambang, Lembong Elazmanawati, Marta Herlina
Departement of Food Industrial Technology, Faculty of Agro-Industrial Technology, Universitas Padjadjaran, Sumedang 45363, Indonesia.
Polymers (Basel). 2023 Jul 29;15(15):3239. doi: 10.3390/polym15153239.
Corn starch-based nanocomposite films usually have low moisture barrier properties. Adding virgin coconut oil (VCO) as a hydrophobic component can improve the nanocomposite film's characteristics, especially the film's permeability and elongation properties. This study aimed to determine the role of VCO with various concentrations (0, 3, 5 wt%) on the physical, mechanical, and water vapor transmission characteristics of corn starch/NCC-based nanocomposite films. Adding 3% VCO to the film showed the lowest WVTR value by 4.721 g/m.h. At the same time, the value of tensile strength was 4.243 MPa, elongation 69.28%, modulus of elasticity 0.062 MPa, thickness 0.219 mm, lightness 98.77, and water solubility 40.51%. However, adding 5 wt% VCO to the film increased the film's elongation properties by 83.87%. The SEM test showed that adding VCO formed a finer structure with pores in several areas. The FTIR films showed that adding VCO caused a slightly higher absorption peak shift at the O-H groups and new absorption peaks at wave numbers 1741 cm and 1742 cm. The results of this study may provide opportunities for the development of nanocomposite films as biodegradable packaging in the future.
基于玉米淀粉的纳米复合薄膜通常具有较低的防潮性能。添加初榨椰子油(VCO)作为疏水性成分可以改善纳米复合薄膜的特性,尤其是薄膜的渗透性和伸长性能。本研究旨在确定不同浓度(0、3、5 wt%)的VCO对基于玉米淀粉/纳米纤维素(NCC)的纳米复合薄膜的物理、机械和水蒸气透过特性的作用。向薄膜中添加3%的VCO时,水蒸气透过率(WVTR)值最低,为4.721 g/m·h。同时,拉伸强度值为4.243 MPa,伸长率为69.28%,弹性模量为0.062 MPa,厚度为0.219 mm,亮度为98.77,水溶性为40.51%。然而,向薄膜中添加5 wt%的VCO使薄膜的伸长性能提高了83.87%。扫描电子显微镜(SEM)测试表明,添加VCO形成了更精细的结构,在几个区域有孔隙。傅里叶变换红外光谱(FTIR)测试表明,添加VCO导致在O-H基团处吸收峰略有更高的位移,并在波数1741 cm和1742 cm处出现新的吸收峰。本研究结果可能为未来开发作为可生物降解包装的纳米复合薄膜提供机会。