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用于增强微波吸收的、具有包裹在碳纳米纤维中的钴纳米颗粒的一维磁性复合材料的设计与合成。

Design and synthesis of one-dimensional magnetic composites with Co nanoparticles encapsulated in carbon nanofibers for enhanced microwave absorption.

作者信息

Ma Mingliang, Hu Jinhu, Han Xukang, Liu Jiao, Jiang Jialin, Feng Chao, Hou Yongbo, Ma Yong

机构信息

School of Civil Engineering, Qingdao University of Technology, Qingdao 266520, Shandong, China.

School of Civil Engineering, Qingdao University of Technology, Qingdao 266520, Shandong, China.

出版信息

J Colloid Interface Sci. 2023 Dec 15;652(Pt A):680-691. doi: 10.1016/j.jcis.2023.08.031. Epub 2023 Aug 7.

Abstract

With the increased usage of electromagnetic microwaves (EM) in wireless communication technology, the problem of electromagnetic radiation pollution has grown dramatically. This study successfully prepared novel Co/C magnetic nanocomposite fibers for EM absorption using the electrospinning and carbonization methods. The morphology, composition, magnetic properties, and EM absorption performance were extensively characterized. This material shows exceptional EM absorption performance, achieving -72.01 dB (at 2.08 mm) for minimum reflection loss (RL) and 5.4 GHz (at 1.68 mm) for effective absorption bandwidth (EAB). The performance surpasses not only any single precursor but also stands as the best in similar investigations. It can be attributed to the microstructure of magnetic Co nanoparticles encapsulated in carbon nanofibers and the macrostructure of cross-linked three-dimensional (3D) conductive networks. The combination of these structures resulted in excellent dielectric loss, magnetic loss, and impedance matching. This research offers new insights into the production of one-dimensional (1D) carbon-based absorbers, while also establishing a theoretical foundation for exploring the application potential of this material. These findings may contribute to the development of more efficient and practical EM absorption materials in the future.

摘要

随着电磁微波(EM)在无线通信技术中的使用增加,电磁辐射污染问题急剧增长。本研究采用静电纺丝和碳化方法成功制备了用于吸波的新型Co/C磁性纳米复合纤维。对其形貌、成分、磁性和吸波性能进行了广泛表征。这种材料表现出优异的吸波性能,最小反射损耗(RL)在2.08毫米处达到-72.01 dB,有效吸收带宽(EAB)在1.68毫米处为5.4 GHz。该性能不仅超过任何单一前驱体,而且在类似研究中也是最佳的。这可归因于包裹在碳纳米纤维中的磁性Co纳米颗粒的微观结构和交联三维(3D)导电网络的宏观结构。这些结构的结合导致了优异的介电损耗、磁损耗和阻抗匹配。本研究为一维(1D)碳基吸收剂的制备提供了新的见解,同时也为探索这种材料的应用潜力奠定了理论基础。这些发现可能有助于未来开发更高效、实用的吸波材料。

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