Pedugu Sivaraman Sushmitha, Krishna Kumar Sangeetha, Srinivasan Prabhakaran, Madhu Deepan Kumar, Kancharlapalli Chinaraga Pitchaiah, Nagarajan Sivaraman, C V S Rao Brahmmananda, Deivasigamani Prabhakaran, Mohan Akhila Maheswari
Department of Chemistry, School of Advanced Sciences, Vellore Institute of Technology (VIT), Vellore 632014, Tamil Nadu, India.
Department of Chemistry, K. Ramakrishnan College of Technology, Samayapuram, Tiruchirappalli 621112, Tamil Nadu, India.
J Hazard Mater. 2023 Oct 5;459:132248. doi: 10.1016/j.jhazmat.2023.132248. Epub 2023 Aug 8.
This work demonstrates the fabrication of a simple, low-cost naked-eye colorimetric solid-state sensor model for selective sensing of Cd. The sensor was developed using a polymer monolithic architect; namely, poly(n-allylthiourea-co-ethyleneglycol dimethacrylate) (poly(ATU-co-EGD) imbued with the chromophoric probe, 3-(quinoline-8-yldiazenyl)quinoline-2,4-diol (QYQD). The concocted indigenous perforated structural assemblies were studied through various microscopic, spectroscopic, and diffraction techniques. The template possessed a uniform arrangement of interconnected macro/mesoporous networks available for the maximum hooking of the QYQD probe moieties for the rapid and enhanced Cd sensing process. The developed sensor offered an enhanced solid-state color transition response from yellow to dark meron for a proportional concentration increase of Cd exhibiting precise absorption spectra with λ at 475 nm. The relative stoichiometric binding ratio of the QYQD probe with Cd was observed to be 2:1. The enhanced working conditions of the developed poly(ATU-co-EGD)QYQD sensor were tuned by validating various analytical conditions. The sensor exhibited a linear response signal from 2 to 150 ppb of Cd, and the corresponding LOD and LOQ values were 0.31 and 1.03 ppb, respectively. The efficacious performance drive of the sensor was validated in real water and cigarette samples that showed excellent data accuracy with a recovery value of ≥ 99.72% (n = 3).
