Gulhan Hazal, Dizaji Reza Faraji, Hamidi Muhammed Nimet, Abdelrahman Amr Mustafa, Basa Safak, Kurt Ece Sagır, Koyuncu Ismail, Guven Huseyin, Ozgun Hale, Ersahin Mustafa Evren, Ozturk Izzet
Istanbul Technical University, Civil Engineering Faculty, Environmental Engineering Department, Ayazaga Campus, Maslak 34469, Istanbul, Turkey.
Istanbul Technical University, Civil Engineering Faculty, Environmental Engineering Department, Ayazaga Campus, Maslak 34469, Istanbul, Turkey.
Sci Total Environ. 2023 Nov 25;901:166431. doi: 10.1016/j.scitotenv.2023.166431. Epub 2023 Aug 19.
Coagulants such as aluminum sulfate (Al(SO) (alum)) and ferric chloride (FeCl) used in water treatment plants (WTPs) led to the generation of sludge that is usually disposed to landfills. However, the utilization of WTP sludge is being encouraged by authorities to achieve sustainable development. This study aims to investigate WTP sludge utilization in a pilot-scale high-rate activated sludge (HRAS) system as a substitute for conventional coagulants. Based on jar tests, the iron sludge was selected for pilot-scale testing due to its superior ability to enhance the treatment efficiency of the HRAS process compared to alum sludge. Iron sludge addition (20.1 ± 1.6 mg dry sludge/L wastewater) slightly improved the removal efficiency of particulate chemical oxygen demand (pCOD) from 74 % to 81 % (p-value: 0.014). Iron sludge addition had a distinct effect on the sludge characteristics of the HRAS process. The average median particle size (d) increased from 96 ± 3 to 163 ± 14 μm (p-value<0.00) with the addition of iron sludge, which improved the settleability of the HRAS process sludge. However, the biochemical methane potential (BMP) of the HRAS process sludge decreased by 8.9 % (p-value<0.00) after iron sludge addition. In a scenario analysis of WTP sludge use in a hypothetical HRAS plant, the effluent quality index (EQI), an indicator of environmental impact, was calculated and the cost related to the operation (the transfer and landfill disposal of WTP and HRAS process sludge, energy and chemical consumption of the HRAS plant) was estimated. As a result, using WTP sludge in the HRAS plant did not significantly affect the EQI of the plant but decreased overall cost by 11 %. The results showed that the use of WTP sludge as a coagulant in wastewater treatment could achieve mutual benefits for WTPs and WWTPs and have the potential to realize the circular economy model.
水处理厂(WTPs)中使用的硫酸铝(Al(SO) (明矾))和氯化铁(FeCl)等凝结剂会产生通常被运往垃圾填埋场处理的污泥。然而,当局正在鼓励对WTP污泥进行利用以实现可持续发展。本研究旨在调查中试规模的高速活性污泥(HRAS)系统中WTP污泥作为传统凝结剂替代品的利用情况。基于烧杯试验,由于与明矾污泥相比,铁污泥在提高HRAS工艺处理效率方面具有更优越的能力,因此选择铁污泥进行中试规模测试。添加铁污泥(20.1 ± 1.6 mg干污泥/升废水)使颗粒化学需氧量(pCOD)的去除效率从74%略微提高到81%(p值:0.014)。添加铁污泥对HRAS工艺的污泥特性有显著影响。添加铁污泥后,平均中位粒径(d)从96 ± 3增加到163 ± 14 μm(p值<0.00),这提高了HRAS工艺污泥的沉降性能。然而,添加铁污泥后,HRAS工艺污泥的生化甲烷潜力(BMP)下降了8.9%(p值<0.00)。在一个假设的HRAS工厂中对WTP污泥使用情况的情景分析中,计算了作为环境影响指标的出水水质指数(EQI),并估算了与运营相关的成本(WTP和HRAS工艺污泥的转运和填埋处置、HRAS工厂的能源和化学消耗)。结果表明,在HRAS工厂中使用WTP污泥对工厂的EQI没有显著影响,但总成本降低了11%。结果表明,在废水处理中使用WTP污泥作为凝结剂可为WTP和污水处理厂带来互利,并有可能实现循环经济模式。