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第一行过渡金属的3,5-二甲基吡啶五水合硫酸盐配合物：[(3,5-二甲基吡啶)(H₂O)]₂SO₄，其中 = 锰、钴、镍和锌。

3,5-Lutidine penta-aqua sulfate complexes of first-row transition metals: [(3,5-lutidine)(HO)]SO, with = Mn, Co, Ni, and Zn.

作者信息

Golen James A, Manke David R

机构信息

University of Massachusetts Dartmouth, 285 Old Westport Road, North Dartmouth, MA 02747, USA.

出版信息

Acta Crystallogr E Crystallogr Commun. 2023 Jun 16;79(Pt 7):648-651. doi: 10.1107/S2056989023005261. eCollection 2023 Jun 1.

DOI:10.1107/S2056989023005261
PMID:37601571
原文链接:https://pmc.ncbi.nlm.nih.gov/articles/PMC10439421/
Abstract

The reactions of MnSO·HO, CoSO·7HO, NiSO·6HO and ZnSO·7HO with 3,5-lutidine (3,5-di-methyl-pyridine) yield crystals of penta-aqua-(3,5-di-methyl-pyridine-κ)manganese(II) sulfate, [Mn(CHN)(HO)]SO, (), penta-aqua-(3,5-di-methyl-pyridine-κ)cobalt(II) sulfate, [Co(CHN)(HO)]SO, (), penta-aqua-(3,5-di-methyl-pyridine-κ)nickel(II) sulfate, [Ni(CHN)(HO)]SO, (), and penta-aqua-(3,5-di-methyl-pyridine-κ)zinc(II) sulfate, [Zn(CHN)(HO)]SO, (), which were characterized by single-crystal X-ray diffraction. The four crystals are isostructural, demonstrating near identical unit-cell parameters and atomic positions. The metal atoms are all octa-hedrally coordinated, with one lutidine ligand and five water ligands. The sulfate dianion hydrogen bonds with the coordinated water mol-ecules of the dicationic metal complex salts, generating infinite three-dimensional networks.

摘要

硫酸锰一水合物（MnSO₄·H₂O）、硫酸钴七水合物（CoSO₄·7H₂O）、硫酸镍六水合物（NiSO₄·6H₂O）和硫酸锌七水合物（ZnSO₄·7H₂O）与3,5-二甲基吡啶反应生成五水合（3,5-二甲基吡啶-κ）硫酸锰（II）晶体[Mn(C₇H₉N)(H₂O)₅]SO₄（I）、五水合（3,5-二甲基吡啶-κ）硫酸钴（II）晶体[Co(C₇H₉N)(H₂O)₅]SO₄（II）、五水合（3,5-二甲基吡啶-κ）硫酸镍（II）晶体[Ni(C₇H₉N)(H₂O)₅]SO₄（III）和五水合（3,5-二甲基吡啶-κ）硫酸锌（II）晶体[Zn(C₇H₉N)(H₂O)₅]SO₄（IV），这些晶体通过单晶X射线衍射进行了表征。这四种晶体结构相同，展示出几乎相同的晶胞参数和原子位置。金属原子均为八面体配位，有一个二甲基吡啶配体和五个水分子配体。硫酸根阴离子与二价金属络合物盐的配位水分子形成氢键，生成无限的三维网络结构。

https://cdn.ncbi.nlm.nih.gov/pmc/blobs/e72e/10439421/1b69b03b5a6c/e-79-00648-fig2.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/e72e/10439421/c53bdb5fef52/e-79-00648-fig1.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/e72e/10439421/1b69b03b5a6c/e-79-00648-fig2.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/e72e/10439421/c53bdb5fef52/e-79-00648-fig1.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/e72e/10439421/1b69b03b5a6c/e-79-00648-fig2.jpg

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本文引用的文献

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From 1D to 2D Cd(II) and Zn(II) Coordination Networks by Replacing Monocarboxylate with Dicarboxylates in Partnership with Azine Ligands: Synthesis, Crystal Structures, Inclusion, and Emission Properties.从 1D 到 2D 的 Cd(II)和 Zn(II)配位网络，通过用二羧酸取代一元羧酸与嗪配体协同作用：合成、晶体结构、包合和发光性质。
Molecules. 2020 Nov 29;25(23):5616. doi: 10.3390/molecules25235616.
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The varied structures of cobalt(II)-pyridine (py)-sulfate: [Co(SO)(py)] , [Co(SO)(py)] , and [Co(SO)(py)] .
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