Xie Mingfa, Liu Jinyuan, Dai Lianghong, Peng Hongjian, Xie Youqing
College of Chemistry and Chemical Engineering, Central South University Changsha 410083 China
RSC Adv. 2023 Aug 18;13(35):24699-24730. doi: 10.1039/d3ra04345b. eCollection 2023 Aug 11.
At present, porphyrin is developing rapidly in the fields of medicine, energy, catalysts, More and more reports on its application are being published. This paper mainly takes the ingenious utilization of porphyrin derivatives in perovskite solar cells, dye-sensitized solar cells, and lithium batteries as the background to review the design idea of functional materials based on the porphyrin structural unit in the energy sector. In addition, the modification and improvement strategies of porphyrin are presented by visually showing the molecular structures or the design synthesis routes of its functional materials. Finally, we provide some insights into the development of novel energy storage materials based on porphyrin frameworks.
目前，卟啉在医学、能源、催化剂等领域发展迅速，关于其应用的报道越来越多。本文主要以卟啉衍生物在钙钛矿太阳能电池、染料敏化太阳能电池和锂电池中的巧妙应用为背景，综述能源领域基于卟啉结构单元的功能材料的设计思路。此外，通过直观展示其功能材料的分子结构或设计合成路线，介绍了卟啉的改性和改进策略。最后，我们对基于卟啉骨架的新型储能材料的发展提供了一些见解。
