基于由[4 + 4]环加成驱动的一维锌配位聚合物晶体的光机械效应。
Photomechanical effects based on a one-dimensional Zn coordination polymer crystal driven by [4 + 4] cycloaddition.
作者信息
Chen Yanlin, Yu Chunjiao, Zhu Xiaotong, Yu Qi
机构信息
Shandong Provincial Key Laboratory of Molecular Engineering, College of Chemistry and Chemical Engineering, Qilu University of Technology (Shandong Academy of Science), Jinan, 250353, People's Republic of China.
College of Chemistry and Chemical Engineering, Qingdao University, Shandong 266071, People's Republic of China.
出版信息
Dalton Trans. 2023 Sep 13;52(35):12194-12197. doi: 10.1039/d3dt02088f.
Photomechanical crystals are promising candidates for photo actuators due to their ability to convert light energy into mechanical energy. We synthesized a coordination polymer crystal that can undergo [4 + 4] cycloaddition reactions with mechanical motion. The inclusion of {[ZnL(4,4'-bipy)(CHOH)]} in a polymer membrane significantly magnified the actuation behavior.
光机械晶体因其能够将光能转化为机械能，是光致动器的理想候选材料。我们合成了一种能够通过机械运动进行[4 + 4]环加成反应的配位聚合物晶体。在聚合物膜中加入{[ZnL(4,4'-联吡啶)(CHOH)]}显著增强了致动行为。
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