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Performance evaluation and stabilization mechanism of red clay treated with polyurethane.

作者信息

Tan Peiling, Wang Fuming, Guo Chengchao, Liu Jun, Lei Qin, Liu Zhixia

机构信息

School of Civil Engineering, Sun Yat-sen University, Zhuhai 519082, China; Guangdong Key Laboratory of Marne Civil Engineering, Guangzhou 510275, China; Guangdong Engineering Technology Research Center for Underground Space Development, Guangzhou 510275, China.

School of Civil Engineering, Sun Yat-sen University, Zhuhai 519082, China; Guangdong Key Laboratory of Marne Civil Engineering, Guangzhou 510275, China; Guangdong Engineering Technology Research Center for Underground Space Development, Guangzhou 510275, China.

出版信息

Chemosphere. 2023 Nov;340:139864. doi: 10.1016/j.chemosphere.2023.139864. Epub 2023 Aug 22.

Abstract

Red clay, a widely distributed soil, weakens significantly when exposed to water. This poses challenges for using it as a foundation for urban infrastructure, as rainwater scouring, infiltration, and external loads can cause uneven settlement and landslides, compromising structural integrity. To address this issue, we propose the use of a green highly permeable water-soluble polyurethane material (PSP) as an alternative to conventional curing agents. We conducted a series of tests to evaluate the efficacy of PSP in improving the mechanical properties of red clay. Acoustic emission tests were used to examine the failure mode of PSP-stabilized red clay, while scanning electron microscopy provided microscopic insights into clay stabilization mechanisms. The triaxial test results establish empirical relationships between strength, stiffness, toughness, and control parameters (PSP content, moisture content, and confining pressure) of the stabilized clay. We found that PSP-stabilized soils exhibit ductile failure and strain hardening, with PSP curing agents effectively enhancing clay strength and stiffness within a 3-day curing period. Univariate analysis reveals positive correlations between peak energy absorption values, peak stress rates, and PSP content, while showing a negative correlation with moisture content. Confining pressure variations have relatively little effect on peak stress ratios of PSP soils, and PSP soil stiffness minimally influences confining pressure as PSP content increases. Importantly, PSP treatment significantly increases ductility compared to untreated clay soils, distinguishing PSP soils from hydric soils.

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