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陶瓷在冷却过程中釉面裂纹的起源与演变

Origin and Evolution of Cracks in the Glaze Surface of a Ceramic during the Cooling Process.

作者信息

Chen Tiantian, Gong Bin, Tang Chun'an

机构信息

School of Resources and Civil Engineering, Northeastern University, Shenyang 110819, China.

Department of Civil and Environmental Engineering, Brunel University London, London UB8 3PH, UK.

出版信息

Materials (Basel). 2023 Aug 8;16(16):5508. doi: 10.3390/ma16165508.

Abstract

Because of the significant difference between the thermal expansion coefficients of ceramic blank and glaze, the glaze typically undergoes more pronounced shrinkage than the blank during ceramic cooling, which results in high stress concentrations and cracking. In this study, the mechanical mechanism of glaze cracking is studied, based on the statistical strength theory, damage mechanics, and continuum mechanics. Furthermore, the influence of the glaze layer thickness, heat transfer coefficient, expansion coefficient, and temperature difference on the creation and propagation of inner microcracks is systematically investigated, and the final discrete fracture network of ceramics is discussed at the specific crack saturation state. The results show that (1) a higher heat transfer coefficient will lead to a more uniform distribution of the surface temperature and a faster cooling process of the ceramics, reducing the number of microcracks when the ambient temperature is reached; (2) the thinner glaze layer is less prone to cracking when its thickness is smaller than that of the blank. However, when the thickness of the glaze layer is similar to that of the blank, the increased thickness of the glaze layer will increase the number of cracks on its surface; and (3) when the expansion coefficient of the glaze layer is smaller than that of the blank, cracks will not occur inside the glaze layer. However, as the coefficient of the thermal expansion of the glaze layer continuously rises, the number of cracks on its surface will first increase and then decrease.

摘要

由于陶瓷坯体和釉料的热膨胀系数存在显著差异,在陶瓷冷却过程中,釉料通常比坯体经历更明显的收缩,这导致高应力集中和开裂。在本研究中,基于统计强度理论、损伤力学和连续介质力学,研究了釉裂的力学机制。此外,系统地研究了釉层厚度、传热系数、膨胀系数和温差对内部微裂纹产生和扩展的影响,并在特定裂纹饱和度状态下讨论了陶瓷最终的离散断裂网络。结果表明:(1)较高的传热系数会导致陶瓷表面温度分布更均匀,冷却过程更快,在达到环境温度时减少微裂纹的数量;(2)当釉层厚度小于坯体厚度时,较薄的釉层不易开裂。然而,当釉层厚度与坯体厚度相似时,釉层厚度的增加会增加其表面的裂纹数量;(3)当釉层的膨胀系数小于坯体的膨胀系数时,釉层内部不会出现裂纹。然而,随着釉层热膨胀系数不断升高,其表面的裂纹数量将先增加后减少。

https://cdn.ncbi.nlm.nih.gov/pmc/blobs/027a/10456388/ed2da1a399f5/materials-16-05508-g001.jpg

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