Qin Jiaxin, Cao Yupeng, Shi Weidong, Wang Zhengang, Qiu Ming
School of Mechanical Engineering, Nantong University, Nantong 226019, China.
Nantong COSCO Shipping Engineering Co., Ltd., Nantong 226006, China.
Materials (Basel). 2023 Aug 10;16(16):5566. doi: 10.3390/ma16165566.
To investigate the effect of laser shock peening parameters on the corrosion resistance of an E690 high-strength steel cladding layer, NVE690 high-strength steel powder was selected for testing at various power densities of pulse lasers. The surface roughness and residual stress of the treated samples were measured, and the microstructure morphology of the sample surface was observed. The electrochemical corrosion tests were conducted with an electrochemical workstation to measure the electrometer polarization, obtain the impedance curve, and observe the electrochemical corrosion. As the laser power density increased, the surface grains of the E690 high-strength steel cladding layer continued to refine until nanocrystals formed, and the residual compressive stress on the surface increased. The residual compressive stress on the surface rendered the passivation film stable and dense; furthermore, the refinement of surface grains inhibited the initiation and propagation of microcracks. The positive shift of the corrosion potential increased from -1.004 to -0.771 V, the corrosion current density decreased from 114.5 to 5.41 μA/cm, the radius of the impedance spectrum curve increased, and the peeling pits, as well as corrosion micropores on the surface, gradually became no longer evident after electrochemical corrosion. After laser shock treatment, the corrosion resistance of the cladding layer sample was substantially improved.
为研究激光冲击强化参数对E690高强钢熔覆层耐蚀性的影响,选用NVE690高强钢粉末在不同功率密度的脉冲激光下进行试验。测量了处理后样品的表面粗糙度和残余应力,并观察了样品表面的微观组织形态。利用电化学工作站进行电化学腐蚀试验,测量静电计极化,获得阻抗曲线,并观察电化学腐蚀情况。随着激光功率密度的增加,E690高强钢熔覆层的表面晶粒不断细化直至形成纳米晶,表面残余压应力增大。表面残余压应力使钝化膜稳定致密;此外,表面晶粒的细化抑制了微裂纹的萌生和扩展。腐蚀电位正向移动,从-1.004 V增大到-0.771 V,腐蚀电流密度从114.5 μA/cm减小到5.41 μA/cm,阻抗谱曲线半径增大,电化学腐蚀后表面的剥落坑和腐蚀微孔逐渐不再明显。激光冲击处理后,熔覆层样品的耐蚀性得到显著提高。