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三种硫酸钙对自密实修补砂浆早期水化及工作性影响的研究

Study on the Effect of Three Types of Calcium Sulfate on the Early Hydration and Workability of Self-Compacting Repair Mortar.

作者信息

Ding Hao, Shen Xuepeng, Chen Aili, Gu Rulin, Fang Ying, Li Dongxu

机构信息

College of Materials Science and Engineering, Nanjing Tech University, Nanjing 210009, China.

Nanjing Kunchang New Material Co., Ltd., Nanjing 210000, China.

出版信息

Materials (Basel). 2023 Aug 16;16(16):5648. doi: 10.3390/ma16165648.

DOI:10.3390/ma16165648
PMID:37629938
原文链接:https://pmc.ncbi.nlm.nih.gov/articles/PMC10456560/
Abstract

Despite having a high early mechanical strength and using sulfoaluminate cement as the primary cementitious material, self-compacting repair mortar (SCRM) suffers from rapid hydration rates leading to construction time constraints. This study examined how several forms of calcium sulfate, including hemihydrate gypsum, anhydrite, and dihydrate gypsum, affected SCRM's workability, hydration process, and microstructure. The outcomes demonstrated that adding hemihydrate gypsum sped up SCRM's early hydration rate and boosted its expansion rate. For a cement with 8% hemihydrate gypsum, 6 h after adding the water, the flexural strength and compressive strength increased by 39.02% and 34.08%, respectively. The hydration rate of SCRM can be efficiently delayed by dihydrate gypsum, although the result is subpar. The material exhibited the lowest fluidity loss in 20 min, the setting time was extended, and the 28-day flexural and compressive strengths were raised by 26.56% and 28.08%, respectively, after adding 8 percent anhydrite.

摘要

尽管自密实修复砂浆(SCRM)具有较高的早期机械强度,并使用硫铝酸盐水泥作为主要胶凝材料,但其水化速度过快,导致施工时间受限。本研究考察了几种硫酸钙形式,包括半水石膏、硬石膏和二水石膏,对SCRM工作性、水化过程和微观结构的影响。结果表明,添加半水石膏加快了SCRM的早期水化速度并提高了其膨胀率。对于含有8%半水石膏的水泥,加水6小时后,抗折强度和抗压强度分别提高了39.02%和34.08%。二水石膏可有效延缓SCRM的水化速度,不过效果欠佳。添加8%硬石膏后,该材料在20分钟内的流动性损失最低,凝结时间延长,28天抗折强度和抗压强度分别提高了26.56%和28.08%。

https://cdn.ncbi.nlm.nih.gov/pmc/blobs/3606/10456560/e4cdcd64f461/materials-16-05648-g007.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/3606/10456560/964312fbe4c8/materials-16-05648-g001.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/3606/10456560/117170679875/materials-16-05648-g002.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/3606/10456560/ae02fb5bfdcf/materials-16-05648-g003.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/3606/10456560/1833152a797a/materials-16-05648-g004.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/3606/10456560/668ec540c10d/materials-16-05648-g005.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/3606/10456560/6ce156ede97a/materials-16-05648-g006.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/3606/10456560/e4cdcd64f461/materials-16-05648-g007.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/3606/10456560/964312fbe4c8/materials-16-05648-g001.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/3606/10456560/117170679875/materials-16-05648-g002.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/3606/10456560/ae02fb5bfdcf/materials-16-05648-g003.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/3606/10456560/1833152a797a/materials-16-05648-g004.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/3606/10456560/668ec540c10d/materials-16-05648-g005.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/3606/10456560/6ce156ede97a/materials-16-05648-g006.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/3606/10456560/e4cdcd64f461/materials-16-05648-g007.jpg

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本文引用的文献

1
Volume Deformation and Hydration Behavior of Ordinary Portland Cement/Calcium Sulfoaluminate Cement Blends.普通硅酸盐水泥/硫铝酸钙水泥混合料的体积变形与水化行为
Materials (Basel). 2023 Mar 27;16(7):2652. doi: 10.3390/ma16072652.
2
Synergistic Effect and Mechanism of Nano-C-S-H Seed and Calcium Sulfoaluminate Cement on the Early Mechanical Properties of Portland Cement.纳米C-S-H晶种与硫铝酸钙水泥对硅酸盐水泥早期力学性能的协同作用及机理
Materials (Basel). 2023 Feb 13;16(4):1575. doi: 10.3390/ma16041575.
3
Influence of Lowered Temperature on Efficiency of Concrete Repair with Polymer-Cement Repair Mortars.
降低温度对聚合物水泥修补砂浆修复混凝土效率的影响。
Materials (Basel). 2020 Sep 24;13(19):4254. doi: 10.3390/ma13194254.